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Crystal structure of bis-(diiso-propyl-ammonium) molybdate.

ABSTRACT: The organic-inorganic title salt, (C6H16N)2[MoO4] or ( i Pr2NH2)2[MoO4], was obtained by reacting MoO3 with diiso-propyl-amine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetra-hedral configuration. In the crystal structure, the diiso-propyl-ammmonium ( i Pr2NH2)+ cations and [MoO4]2- anions are linked to each other through N-H?O hydrogen bonds, generating rings with R 12 12(36) motifs that give rise to the formation of a three-dimensional network. The structure was refined taking into account inversion twinning (ratio of ca 4:1 between the two domains).

SUBMITTER: Sarr B

PROVIDER: S-EPMC6218890 | biostudies-other | 2018 Nov

REPOSITORIES: biostudies-other

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Crystal structure of bis-(diiso-propyl-ammonium) molybdate.

Sarr Bougar B Mbaye Abdou A Diop Cheikh Abdoul Khadir CAK Melin Frederic F Hellwig Petra P Sidibé Mamadou M Rousselin Yoann Y

Acta crystallographica. Section E, Crystallographic communications 20181031 Pt 11

The organic-inorganic title salt, (C6H16N)2[MoO4] or ( i Pr2NH2)2[MoO4], was obtained by reacting MoO3 with diiso-propyl-amine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetra-hedral configuration. In the crystal structure, the diiso-propyl-ammmonium ( i Pr2NH2)< ...[more]

PMID: 30443406

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Crystal structure of bis-(cyclo-hexyl-ammonium) di-phenyl-dioxalatostannate(IV).

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Crystal structure of bis-(propane-1,3-di-ammonium) hexa-fluorido-aluminate fluoride trihydrate.

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Crystal structure of the bis-(cyclo-hexyl-ammonium) succinate succinic acid salt adduct.

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