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{Bis[2-(diphenyl-phosphan-yl)phen-yl] ether-?P,P'}(1,1'-dibenz-yl-1H,1'H-4,4'bi-1,2,3-triazole-?N,N)copper(I) hexa-fluorido-phosphate dichloro-methane hemisolvate.

ABSTRACT: In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis-[(diphenyl-phosphan-yl)phen-yl] ether and Bn-bta = 1,1'-dibenzyl-1H,1'H-4,4'-bi-1,2,3triazol-e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra-hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.

SUBMITTER: Monkowius U 

PROVIDER: S-EPMC2915126 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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{Bis[2-(diphenyl-phosphan-yl)phen-yl] ether-κP,P'}(1,1'-dibenz-yl-1H,1'H-4,4'bi-1,2,3-triazole-κN,N)copper(I) hexa-fluorido-phosphate dichloro-methane hemisolvate.

Monkowius Uwe U   Ritter Stefan S   König Burkhard B   Yersin Hartmut H   Zabel Manfred M  

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis-[(diphenyl-phosphan-yl)phen-yl] ether and Bn-bta = 1,1'-dibenzyl-1H,1'H-4,4'-bi-1,2,3triazol-e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra-hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical pa  ...[more]

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