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[4'-(2-Bromo-5-pyrid-yl)-2,2':6',2''-terpyridine-?N,N',N'']bis(triphenyl-phosphine-?P)-copper(I) tetra-fluorido-borate dichloro-methane hemisolvate.

ABSTRACT: In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra-hedral arrangement, coordinated by two triphenyl-phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol-ecule of dichloro-methane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine inter-acts weakly with the copper centre at a distance of 3.071?Å.

SUBMITTER: Polson MI

PROVIDER: S-EPMC2915135 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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[4'-(2-Bromo-5-pyrid-yl)-2,2':6',2''-terpyridine-κN,N',N'']bis(triphenyl-phosphine-κP)-copper(I) tetra-fluorido-borate dichloro-methane hemisolvate.

Polson Matthew I J MI Hanan Garry S GS Taylor Nicholas J NJ

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title complex, [Cu(C(20)H(13)BrN(4))(C(18)H(15)P)(2)]BF(4)·0.5CH(2)Cl(2), the copper(I) cation adopts a distorted tetra-hedral arrangement, coordinated by two triphenyl-phosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-mol-ecule of dichloro-methane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine inter-acts weakly with the ...[more]

PMID: 21200553

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