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Dibromidobis[2-(dicyclo-hexyl-phosphan-yl)-biphenyl-?P]palladium(II).

ABSTRACT: The title compound, [PdBr(2)(C(24)H(31)P)(2)], has a distorted trans square-planar coordination of the Pd atom, which occupies an inversion centre. The most important bond distances include Pd-P of 2.380?(2)?Å and Pd-Br of 2.515?(2)?Å. Weak inter-molecular ?-? inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.949?(6)?Å] are present via crystallographic inversion centres, resulting in a one-dimensional supra-molecular architecture.

SUBMITTER: Xu C

PROVIDER: S-EPMC2959319 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Dibromidobis[2-(dicyclo-hexyl-phosphan-yl)-biphenyl-κP]palladium(II).

Xu Chen C Li Ying-Fei YF Wang Zhi-Qiang ZQ Cen Fei-Fei FF Zhang Yu-Qing YQ

Acta crystallographica. Section E, Structure reports online 20080930 Pt 10

The title compound, [PdBr(2)(C(24)H(31)P)(2)], has a distorted trans square-planar coordination of the Pd atom, which occupies an inversion centre. The most important bond distances include Pd-P of 2.380 (2) Å and Pd-Br of 2.515 (2) Å. Weak inter-molecular π-π inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.949 (6) Å] are present via crystallographic inversion centres, resulting in a one-dimensional supra-molecular architecture. ...[more]

PMID: 21201078

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