Unknown

Dataset Information

0

Dibromidobis[2-(dicyclo-hexyl-phosphan-yl)-biphenyl-?P]palladium(II).


ABSTRACT: The title compound, [PdBr(2)(C(24)H(31)P)(2)], has a distorted trans square-planar coordination of the Pd atom, which occupies an inversion centre. The most important bond distances include Pd-P of 2.380?(2)?Å and Pd-Br of 2.515?(2)?Å. Weak inter-molecular ?-? inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.949?(6)?Å] are present via crystallographic inversion centres, resulting in a one-dimensional supra-molecular architecture.

SUBMITTER: Xu C 

PROVIDER: S-EPMC2959319 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

altmetric image

Publications

Dibromidobis[2-(dicyclo-hexyl-phosphan-yl)-biphenyl-κP]palladium(II).

Xu Chen C   Li Ying-Fei YF   Wang Zhi-Qiang ZQ   Cen Fei-Fei FF   Zhang Yu-Qing YQ  

Acta crystallographica. Section E, Structure reports online 20080930 Pt 10


The title compound, [PdBr(2)(C(24)H(31)P)(2)], has a distorted trans square-planar coordination of the Pd atom, which occupies an inversion centre. The most important bond distances include Pd-P of 2.380 (2) Å and Pd-Br of 2.515 (2) Å. Weak inter-molecular π-π inter-actions between the benzene rings of adjacent mol-ecules [centroid-centroid distance = 3.949 (6) Å] are present via crystallographic inversion centres, resulting in a one-dimensional supra-molecular architecture. ...[more]

Similar Datasets

| S-EPMC2977585 | biostudies-literature
| S-EPMC2967900 | biostudies-other
| S-EPMC2971950 | biostudies-literature
| S-EPMC2971912 | biostudies-literature
| S-EPMC3569185 | biostudies-literature
| S-EPMC2968301 | biostudies-literature
| S-EPMC3515096 | biostudies-literature
| S-EPMC3200790 | biostudies-literature
| S-EPMC3050419 | biostudies-literature
| S-EPMC2959264 | biostudies-literature