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{Bis[2-(dicyclo-hexyl-phosphino)phen-yl]methyl-silyl-?P,Si,P'}chloridoplatinum(II).

ABSTRACT: In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo-hexyl; cod = cyclo-octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo-hexane rings adopt a chair conformation.

SUBMITTER: Li YH

PROVIDER: S-EPMC2959269 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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{Bis[2-(dicyclo-hexyl-phosphino)phen-yl]methyl-silyl-κP,Si,P'}chloridoplatinum(II).

Li Yong-Hua YH Zhang Yuan Y Zhao Min-Min MM Li Xian X

Acta crystallographica. Section E, Structure reports online 20080917 Pt 10

In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo-hexyl; cod = cyclo-octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo-hexane rings adopt a chair conformation. ...[more]

PMID: 21201023

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{Bis[2-(dicyclo-hexyl-phosphino)-phen-yl]methyl-silyl-?P,Si,P'}chloridopalladium(II).

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Chlorido{[2-(dicyclo-hexyl-phosphano-yl)eth-yl]bis-[2-(dicyclo-hexyl-phosphan-yl)eth-yl]phosphane}platinum(II) chloride dichloro-methane hemisolvate tetra-hydrate.

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| S-EPMC2967900 | biostudies-other

1,4-Bis[4-(dimethyl-silyl)phen-yl]benzene.

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Dicyclo-hexyl-bis-(naphthalen-1-ylmeth-yl)phospho-nium chloride chloro-form disolvate.

Project description:In the title solvated phosphonium salt, C34H40P(+)·Cl(-)·2CHCl3, the two cyclo-hexyl and two 1-naphthyl-methyl groups at the P atom are in a distorted tetra-hedral arrangement [105.26 (6)-113.35 (6)°]. Both cyclo-hexyl rings adopt a chair conformation. The dihedral angle between the naphthyl ring systems is 74.08 (3)°.

| S-EPMC3588969 | biostudies-literature

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| S-EPMC3435591 | biostudies-literature

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