Browse
Submit Data
Databases
API
Help

Dataset Information

36 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[tribenzyl-tin(IV)]-?-4-nitro-cinnamato-?O:O'].

ABSTRACT: The 4-nitro-cinnamate anion in the title compound, [Sn(C(7)H(7))(3)(C(9)H(6)NO(4))](n), bridges adjacent tribenzyl-tin cations into a helical chain running along the b axis. The Sn atoms in the two independent mol-ecules adopt distorted trans-C(3)SnO(2) trigonal-bipyramidal geometries. The repeat distance of the polymeric chain is b/2.

SUBMITTER: Thong PY

PROVIDER: S-EPMC2959618 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[[tribenzyl-tin(IV)]-μ-4-nitro-cinnamato-κO:O'].

Thong Pui Yee PY Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20081011 Pt 11

The 4-nitro-cinnamate anion in the title compound, [Sn(C(7)H(7))(3)(C(9)H(6)NO(4))](n), bridges adjacent tribenzyl-tin cations into a helical chain running along the b axis. The Sn atoms in the two independent mol-ecules adopt distorted trans-C(3)SnO(2) trigonal-bipyramidal geometries. The repeat distance of the polymeric chain is b/2. ...[more]

PMID: 21580842

Similar Datasets

catena-Poly[[tribenzyl-tin(IV)]-μ-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-κO:O'].

Project description:The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl-ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O(covalent) bond by 0.093 (4) Å and in the second mol-ecule, the Sn atom is displaced by 0.105 (4) Å in the same direction.

| S-EPMC2983362 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-μ-(E)-3-(2-fur-yl)prop-2-enoato-κO:O'].

Project description:In the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(7)H(5)O(3))](n), the Sn(IV) atom exists in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry. The polymer propagates as a chain along the a axis. There are two independent formula units in the asymmetric unit; the furyl ring of one of the anions is disordered over two positions in a 0.630 (8):0.370 (8) ratio. The crystal studied was a non-merohedral twin with a minor twin domain of 37.3 (1)%.

| S-EPMC3151990 | biostudies-literature

catena-Poly[[diphenyl-propyl-tin(IV)]-μ-chloroacetato-κO:O'].

Project description:The title compound, [Sn(C(3)H(7))(C(6)H(5))(2)(C(2)H(2)ClO(2))](n), comprises polymeric carboxyl-ate-bridged spiral chains with two monomer formula units in the asymmetric unit. Both Sn centres exhibit similar distorted trigonal-bipyramidal [C(3)SnO(2)] coordination, with the O atoms of the carboyxlate ligands in trans positions.

| S-EPMC2961930 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

| S-EPMC3051585 | biostudies-literature

catena-Poly[[cyclo-hexyl-diphenyl-tin(IV)]-μ-hydroxido-κO:O].

Project description:The title polymeric mixed-organyl tin hydroxide, [Sn(C(6)H(5))(2)(C(6)H(11))(OH)](n), hass a hydroxide-bridged chain structure; the tin center shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The Sn atom lies on a special position of site symmetry m; the symmetry element relates one phenyl ring to the other and also relates one half of the cyclo-hexyl ring to the other half.

| S-EPMC2961296 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-?-4-formyl-2-meth-oxy-6-nitro-phenolato-?O:O].

Project description:The formyl-meth-oxy-nitro-phenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn-O = 2.1227?(12)?Å and Sn? O = 2.4936?(13)?Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the trans-C(3)SnO(2) trigonal-bipyramidal polyhedron in the direction of the covalently-bonded O atom [Sn-O-C = 137.63?(11)°] by 0.247?(1)?Å; the geometry is distorted towards an octa-hedron by a remote O atom of the meth-oxy subsituent [Sn?O = 3.019?(1)?Å].

| S-EPMC3120579 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-quinaldato].

Project description:The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.

| S-EPMC2914916 | biostudies-literature

catena-Poly[[triphenyl-tin(IV)]-μ(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-κO:O]].

Project description:The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H⋯O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand.

| S-EPMC2983217 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-?-(E)-3-phenyl-prop-2-enoato-?O:O'].

Project description:The Sn(IV) atom in the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal-bipyramidal geometry (average covalent Sn-O = 2.167?Å, average dative Sn-O = 2.361?Å and average O-Sn-O = 169.6°). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group.

| S-EPMC3120586 | biostudies-literature

catena-Poly[[di-tert-butyl-tin(IV)]-μ-oxalato].

Project description:The title compound, [Sn(C4H9)2(C2O4)] n , an unexpected side product in the reaction of di-tert-butyl-tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn-O bond lengths of 2.150 (1) and 2.425 (1) Å, and two t-butyl groups with Sn-C bond lengths of 2.186 (2) and 2.190 (2) Å. The coordination polyhedron around the Sn(IV) atom is a distorted tetra-gonal disphenoid. The centrosymmetric oxalate ion also has an asymmetric coordination geometry, as reflected by the two slightly different C-O bond lengths of 1.242 (2) and 1.269 (2) Å. The chains of the polymer propagate along the b-axis direction. Only van der Waals inter-actions are observed between the chains.

| S-EPMC3998617 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data