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Catena-Poly[[tribenzyl-tin(IV)]-?-4-nitro-cinnamato-?O:O'].


ABSTRACT: The 4-nitro-cinnamate anion in the title compound, [Sn(C(7)H(7))(3)(C(9)H(6)NO(4))](n), bridges adjacent tribenzyl-tin cations into a helical chain running along the b axis. The Sn atoms in the two independent mol-ecules adopt distorted trans-C(3)SnO(2) trigonal-bipyramidal geometries. The repeat distance of the polymeric chain is b/2.

SUBMITTER: Thong PY 

PROVIDER: S-EPMC2959618 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[tribenzyl-tin(IV)]-μ-4-nitro-cinnamato-κO:O'].

Thong Pui Yee PY   Lo Kong Mun KM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20081011 Pt 11


The 4-nitro-cinnamate anion in the title compound, [Sn(C(7)H(7))(3)(C(9)H(6)NO(4))](n), bridges adjacent tribenzyl-tin cations into a helical chain running along the b axis. The Sn atoms in the two independent mol-ecules adopt distorted trans-C(3)SnO(2) trigonal-bipyramidal geometries. The repeat distance of the polymeric chain is b/2. ...[more]

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