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Catena-Poly[[tribenzyl-tin(IV)]-μ-(E)-3-(2-fur-yl)prop-2-enoato-κO:O'].

ABSTRACT: In the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(7)H(5)O(3))](n), the Sn(IV) atom exists in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry. The polymer propagates as a chain along the a axis. There are two independent formula units in the asymmetric unit; the furyl ring of one of the anions is disordered over two positions in a 0.630 (8):0.370 (8) ratio. The crystal studied was a non-merohedral twin with a minor twin domain of 37.3 (1)%.

SUBMITTER: Keng TC

PROVIDER: S-EPMC3151990 | biostudies-literature |

REPOSITORIES: biostudies-literature

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catena-Poly[[tribenzyl-tin(IV)]-?-(E)-3-phenyl-prop-2-enoato-?O:O'].

Project description:The Sn(IV) atom in the title carboxyl-ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal-bipyramidal geometry (average covalent Sn-O = 2.167?Å, average dative Sn-O = 2.361?Å and average O-Sn-O = 169.6°). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group.

| S-EPMC3120586 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-μ-4-nitro-cinnamato-κO:O'].

Project description:The 4-nitro-cinnamate anion in the title compound, [Sn(C(7)H(7))(3)(C(9)H(6)NO(4))](n), bridges adjacent tribenzyl-tin cations into a helical chain running along the b axis. The Sn atoms in the two independent mol-ecules adopt distorted trans-C(3)SnO(2) trigonal-bipyramidal geometries. The repeat distance of the polymeric chain is b/2.

| S-EPMC2959618 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-μ-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-κO:O'].

Project description:The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl-ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O(covalent) bond by 0.093 (4) Å and in the second mol-ecule, the Sn atom is displaced by 0.105 (4) Å in the same direction.

| S-EPMC2983362 | biostudies-literature

catena-Poly[[diphenyl-propyl-tin(IV)]-μ-chloroacetato-κO:O'].

Project description:The title compound, [Sn(C(3)H(7))(C(6)H(5))(2)(C(2)H(2)ClO(2))](n), comprises polymeric carboxyl-ate-bridged spiral chains with two monomer formula units in the asymmetric unit. Both Sn centres exhibit similar distorted trigonal-bipyramidal [C(3)SnO(2)] coordination, with the O atoms of the carboyxlate ligands in trans positions.

| S-EPMC2961930 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

| S-EPMC3051585 | biostudies-literature

catena-Poly[[cyclo-hexyl-diphenyl-tin(IV)]-μ-hydroxido-κO:O].

Project description:The title polymeric mixed-organyl tin hydroxide, [Sn(C(6)H(5))(2)(C(6)H(11))(OH)](n), hass a hydroxide-bridged chain structure; the tin center shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The Sn atom lies on a special position of site symmetry m; the symmetry element relates one phenyl ring to the other and also relates one half of the cyclo-hexyl ring to the other half.

| S-EPMC2961296 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-quinaldato].

Project description:The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.

| S-EPMC2914916 | biostudies-literature

catena-Poly[[triphenyl-tin(IV)]-μ(2)-[3-(cyclo-hexyl-carbamo-yl)propanoato-κO:O]].

Project description:The Sn atom in the polymeric title compound, [Sn(C(6)H(5))(3)(C(10)H(16)NO(3))](n), is five-coordinated within a trans-C(3)O(2) donor set that defines an approximate trigonal-bipyramidal geometry. The carboxyl-ate ligand is monodentate and the amide O atom bridges a symmetry-related Sn atom, generating a chain along [010] with a linear topology. An intra-molecular carboxyl-ate-carbonyl N-H⋯O hydrogen bond is responsible for the curved conformation within the carboxyl-ate ligand.

| S-EPMC2983217 | biostudies-literature

catena-Poly[[di-tert-butyl-tin(IV)]-μ-oxalato].

Project description:The title compound, [Sn(C4H9)2(C2O4)] n , an unexpected side product in the reaction of di-tert-butyl-tin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn(IV) atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn-O bond lengths of 2.150 (1) and 2.425 (1) Å, and two t-butyl groups with Sn-C bond lengths of 2.186 (2) and 2.190 (2) Å. The coordination polyhedron around the Sn(IV) atom is a distorted tetra-gonal disphenoid. The centrosymmetric oxalate ion also has an asymmetric coordination geometry, as reflected by the two slightly different C-O bond lengths of 1.242 (2) and 1.269 (2) Å. The chains of the polymer propagate along the b-axis direction. Only van der Waals inter-actions are observed between the chains.

| S-EPMC3998617 | biostudies-literature

catena-Poly[[tribenzyl-tin(IV)]-?-4-formyl-2-meth-oxy-6-nitro-phenolato-?O:O].

Project description:The formyl-meth-oxy-nitro-phenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn-O = 2.1227?(12)?Å and Sn? O = 2.4936?(13)?Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the trans-C(3)SnO(2) trigonal-bipyramidal polyhedron in the direction of the covalently-bonded O atom [Sn-O-C = 137.63?(11)°] by 0.247?(1)?Å; the geometry is distorted towards an octa-hedron by a remote O atom of the meth-oxy subsituent [Sn?O = 3.019?(1)?Å].

| S-EPMC3120579 | biostudies-literature

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