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Catena-Poly[[tribenzyl-tin(IV)]-?-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-?O:O'].

ABSTRACT: The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl-ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial plane in the direction of the Sn-O(covalent) bond by 0.093?(4)?Å and in the second mol-ecule, the Sn atom is displaced by 0.105?(4)?Å in the same direction.

SUBMITTER: Keng TC 

PROVIDER: S-EPMC2983362 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[tribenzyl-tin(IV)]-μ-2-(piperidin-1-ylcarbothio-ylsulfan-yl)acetato-κO:O'].

Keng Thy Chun TC   Lo Kong Mun KM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10

The Sn atom in the title polymeric compound, [Sn(C(7)H(7))(3)(C(8)H(12)NO(2)S(2))](n), exists in a trans-C(3)O(2) trigonal-bipyramidal coordination environment in the two independent formula units. The carboxyl-ate moiety functions in a bridging mode, linking adjacent triorganotin cations into a linear chain running along the shortest axis of the triclinic unit cell; the repeat distance of the polymer is half the a-axial length. In one formula unit, the Sn atom is displaced out of the equatorial  ...[more]

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