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Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).

ABSTRACT: In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H?S hydrogen bonds, forming a three-dimensional network structure.

SUBMITTER: Zhou XX

PROVIDER: S-EPMC2960303 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).

Zhou Xiu-Xia XX Zhou Zheng-Yuan ZY Chen Jian-Qiao JQ Lin Xiao-Ming XM Cai Yue-Peng YP

Acta crystallographica. Section E, Structure reports online 20080109 Pt 2

In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure. ...[more]

PMID: 21201296

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