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Diaqua-[5-(2-pyrid-yl)tetra-zolato-?N,N]manganese(II).

ABSTRACT: The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydro-thermal reaction of Mn(NO(3))(2) with picolino-nitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octa-hedral Mn environment contains two planar trans-related N,N'-chelating 5-(2-pyrid-yl)-tetra-zolate ligands in the equatorial plane and two axial water mol-ecules. O-H?N hydrogen bonds generate an infinite three-dimensional network.

SUBMITTER: Wen XC

PROVIDER: S-EPMC2961478 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Diaqua-[5-(2-pyrid-yl)tetra-zolato-κN,N]manganese(II).

Wen Xiao-Chun XC

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydro-thermal reaction of Mn(NO(3))(2) with picolino-nitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octa-hedral Mn environment contains two planar trans-related N,N'-chelating 5-(2-pyrid-yl)-tetra-zolate ligands in the equatorial plane and two axial water mol-ecules. O-H⋯N hydrogen bonds generate an infinite three-dimensional network. ...[more]

PMID: 21202460

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