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Diaqua-bis[5-(2-pyridylmeth-yl)tetra-zolato-κN,N]manganese(II).

ABSTRACT: The title complex, [Mn(C(7)H(6)N(5))(2)(H(2)O)(2)], was obtained by the in situ hydro-thermal reaction of MnCl(2) with 2-(2-pyrid-yl)acetonitrile in the presence of NaN(3). The Mn(II) atom, which is located on an inversion centre, has a distorted octa-hedral coordination geometry formed by two water mol-ecules and two chelating ligands. Inter-molecular hydrogen bonds and π-π inter-actions (3.452 Å) stabilize the crystal structure and lead to the formation of a three-dimensional network.

SUBMITTER: Wang W

PROVIDER: S-EPMC2961924 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Diaqua-bis[5-(2-pyridylmeth-yl)tetra-zolato-κN,N]manganese(II).

Wang Wei W

Acta crystallographica. Section E, Structure reports online 20080705 Pt 8

The title complex, [Mn(C(7)H(6)N(5))(2)(H(2)O)(2)], was obtained by the in situ hydro-thermal reaction of MnCl(2) with 2-(2-pyrid-yl)acetonitrile in the presence of NaN(3). The Mn(II) atom, which is located on an inversion centre, has a distorted octa-hedral coordination geometry formed by two water mol-ecules and two chelating ligands. Inter-molecular hydrogen bonds and π-π inter-actions (3.452 Å) stabilize the crystal structure and lead to the formation of a three-dimensional network. ...[more]

PMID: 21203093

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