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Chlorido(1,3-dimethyl-thio-urea-?S)bis-(triphenyl-phosphine-?P)copper(I) acetonitrile hemisolvate.

ABSTRACT: The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl-thio-urea (dmtu) and triphenyl-phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra-hedral environment formed by two P atoms from triphenyl-phosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the mol-ecules exhibit intra- and inter-molecular N-H?Cl inter-actions.

SUBMITTER: La-O L

PROVIDER: S-EPMC2977114 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Chlorido(1,3-dimethyl-thio-urea-κS)bis-(triphenyl-phosphine-κP)copper(I) acetonitrile hemisolvate.

La-O Latipah L Pakawatchai Chaveng C Saithong Saowanit S Skelton Brian W BW

Acta crystallographica. Section E, Structure reports online 20090715 Pt 8

The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl-thio-urea (dmtu) and triphenyl-phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra-hedral environment formed by two P atoms from triphenyl-phosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the mol-ecules exhibit intra- and inter-molecular N-H⋯Cl inter-actions. ...[more]

PMID: 21583381

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