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Aqua-bis(triphenyl-phosphine-?P)copper(I) tetra-fluoridoborate.

ABSTRACT: In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl-phosphine ligands and one water mol-ecule in a distorted trigonal geometry. In the BF(4) (-) anion, three F atoms are disordered over two sites around the B-F bond, the site-occupancy ratio being 0.67?(6):0.33?(6). The Cu?F distance of 2.602?(5)?Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter-action. O-H?F and weak C-H?F hydrogen bonding is present in the crystal structure.

SUBMITTER: Dai Y

PROVIDER: S-EPMC2977191 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Aqua-bis(triphenyl-phosphine-κP)copper(I) tetra-fluoridoborate.

Dai Yanfeng Y Zhang Yi Y Tian Jianwen J Liu Zhen Z

Acta crystallographica. Section E, Structure reports online 20090729 Pt 8

In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl-phosphine ligands and one water mol-ecule in a distorted trigonal geometry. In the BF(4) (-) anion, three F atoms are disordered over two sites around the B-F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu⋯F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter-action. O-H⋯F and weak C-H⋯F hydrogen bonding is presen ...[more]

PMID: 21583302

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