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(Methanol-?O)(perchlorato-?O)bis-(triphenyl-phosphine-?P)silver(I).

ABSTRACT: In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl-phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol-ecule. The crystal structure is stablized by a bifurcated inter-molecular O-H?O hydrogen bond, involving the O-H donor from methanol and two acceptor O atoms from the perchlorate anion, so forming a zigzag chain propagating in [010].

SUBMITTER: Cui LN 

PROVIDER: S-EPMC3007358 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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(Methanol-κO)(perchlorato-κO)bis-(triphenyl-phosphine-κP)silver(I).

Cui Li-Na LN   Jin Qiong-Hua QH   Hu Ke-Yi KY   Zhang Cun-Lin CL  

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl-phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol-ecule. The crystal structure is stablized by a bifurcated inter-molecular O-H⋯O hydrogen bond, involving the O-H donor from methanol and two acceptor O atoms from the perchlora  ...[more]

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