Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(2-Amino-5-chloro-benzene-sulfonato)bis-(triphenyl-phosphine)silver(I).

ABSTRACT: The asymmetric unit of the title mononuclear compound, [Ag(C(6)H(5)ClNO(3)S)(C(18)H(15)P)(2)], contains four independent mol-ecules. In each of the mol-ecules, the Ag(I) cation is three-coordinated by two triphenyl-phosphine ligands, and one N atom from a 2-amino-5-chloro-benzene-sulfonate anion. The mol-ecules are linked into a one-dimensional supra-molecular structure by N-H?O hydrogen bonds.

SUBMITTER: Wu H

PROVIDER: S-EPMC2960176 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(2-Amino-5-chloro-benzene-sulfonato)bis-(triphenyl-phosphine)silver(I).

Wu Hua H Gao Li-Li LL Liu Ying-Ying YY

Acta crystallographica. Section E, Structure reports online 20080123 Pt 2

The asymmetric unit of the title mononuclear compound, [Ag(C(6)H(5)ClNO(3)S)(C(18)H(15)P)(2)], contains four independent mol-ecules. In each of the mol-ecules, the Ag(I) cation is three-coordinated by two triphenyl-phosphine ligands, and one N atom from a 2-amino-5-chloro-benzene-sulfonate anion. The mol-ecules are linked into a one-dimensional supra-molecular structure by N-H⋯O hydrogen bonds. ...[more]

PMID: 21201346

Similar Datasets

Poly[(?(3)-4-amino-benzene-sulfonato-?N:O:O)(triphenyl-phosphine-?P)silver(I)].

Project description:In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.

| S-EPMC3006886 | biostudies-other

(2-Amino-5-chloro-benzene-sulfonato-?O)bis-(3-methyl-isoquinoline-?N)silver(I).

Project description:The title compound, [Ag(C(6)H(5)ClNO(3)S)(C(10)H(9)N)(2)], crystallizes with two independent mol-ecules in the asymmetric unit. The Ag(+) cation is three-coordinated by one O atom from the 2-amino-5-chloro-benzene-sulfonate anion and two N atoms from two different 3-methyl-isoquinoline ligands in a slightly distorted trigonal-planar geometry. In the crystal, network of inter-molecular N-H?O hydrogen-bonding inter-actions generates a chain along [100].

| S-EPMC2984077 | biostudies-literature

(Methanol-?O)(perchlorato-?O)bis-(triphenyl-phosphine-?P)silver(I).

Project description:In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl-phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol-ecule. The crystal structure is stablized by a bifurcated inter-molecular O-H?O hydrogen bond, involving the O-H donor from methanol and two acceptor O atoms from the perchlorate anion, so forming a zigzag chain propagating in [010].

| S-EPMC3007358 | biostudies-literature

Bis(2-{[bis-(dimethyl-amino)-methyl-idene]amino-?N}benzene-sulfonato-?N)copper(II).

Project description:The mol-ecular structure of the title compound, [Cu(C11H16N3O3S)2], shows the Cu(II) atom with a distorted square-planar coordination geometry from the N2O2 donor set of the two chelating 2-{[bis-(dimethyl-amino)-methyl-idene]amino}-benzene-sulfonate ligands. The Cu(II) atom lies 0.065?(1)?Å above the N2O2 plane and the Cu-O [2 × 1.945?(2)?Å] and Cu-N bond lengths [1.968?(3) and 1.962?(3)?Å] lie in expected ranges. The two aromatic ring planes make a dihedral angle of 85.48?(1)°.

| S-EPMC3588740 | biostudies-literature

Bis(triphenyl-phosphine-?P)(tropolonato-?O,O')silver(I) dichloro-methane solvate.

Project description:The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.

| S-EPMC2968127 | biostudies-literature

Bis(4-amino-benzene-sulfonato-?N)diaqua-bis(dimethyl-formamide-?O)nickel(II) dihydrate.

Project description:In the title compound, [Ni(C(6)H(6)NO(3)S)(2)(C(3)H(7)NO)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion (site symmetry ) is coordinated by two -NH(2) groups from two 4-amino-benzene-sulfonate anions, two O atoms from two dimethyl-formamide mol-ecules and two water mol-ecules, forming a slightly distorted trans-NiN(2)O(4) octa-hedral geometry. In the crystal structure, inter-molecular O-H?O, O-H?(O,O) and N-H?O hydrogen bonds link the components into a three-dimensional network. The O atoms of the sulfonate group are disordered over two sets of sites in a 0.833?(4):0.167?(4) ratio and the O atom of the uncoordinated water mol-ecule is disordered over two sites in a 0.637?(18):0.363?(18) ratio.

| S-EPMC2969510 | biostudies-literature

Di-μ-aqua-bis-{diaqua-[μ-4-({4-[bis-(2-hy-droxy-eth-yl)amino]-6-chloro-1,3,5-triazin-2-yl}amino)-benzene-sulfonato]-sodium(I)}.

Project description:In the dinuclear title compound, [Na(2)(C(13)H(15)ClN(5)O(5)S)(2)(H(2)O)(6)](n), two Na(+) cations, disposed about a centre of inversion, are linked by two bridging water mol-ecules. The coordination geometry is based on an O(5) donor set defined by four water mol-ecules and a 4-amino-benzene-sulfonate O atom in a distorted trigonal-bipyramidal geometry. In the crystal, significant O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds lead to the formation of a three-dimensional architecture.

| S-EPMC3379186 | biostudies-literature

Bis(2-amino-4-chloro-benzoato)triphenyl-anti-mony(V).

Project description:The title complex mol-ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C(2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl-ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra-molecular N-H?O and C-H?O hydrogen bonds occur.

| S-EPMC2971026 | biostudies-literature

Bis(4-amino-benzene-sulfonato-?O)bis-(propane-1,3-diamine-?N,N')copper(II) dihydrate.

Project description:In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexa-coordinated by four N atoms from two 1,3-diamino-propane ligands and two O atoms from two 4-amino-benzene-sulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octa-hedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O-H?O, N-H?O and N-H?N hydrogen bonds.

| S-EPMC2972104 | biostudies-literature

Penta-aqua-bis[4-(2-hydroxy-benzyl-idene-amino)benzene-sulfonato]lead(II).

Project description:In the structure of the title compound, [Pb(C(13)H(10)NO(4)S)(2)(H(2)O)(5)], two S-O bonds and one C-N bond have lengths of 1.421?(9), 1.425?(8) and 1.268?(11)?Å, respectively, which suggests they are double bonds. Mol-ecules form a two-dimensional layered structure via O-H?O and O-H?N inter-actions. The Pb atom adopts distorted cubo-octahedral coordination.

| S-EPMC2968621 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data