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Poly[1-ethyl-3-methyl-imidazolium [tri-?-chlorido-chromate(II)]].

ABSTRACT: The title compound, {(C(6)H(11)N(2))[CrCl(3)]}(n), was generated via mixing of the ionic liquid 1-ethyl-3-methyl-imidazolium chloride with CrCl(2) in ethanol. Crystals were obtained by a diffusion method. In the crystal structure, the anion forms one-dimensional chains of chloride-bridged Jahn-Teller distorted chromium(II) centers extending along the [100] direction. The imidazolium cations are positioned between these chains.

SUBMITTER: Danford JJ

PROVIDER: S-EPMC2968286 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Poly[1-ethyl-3-methyl-imidazolium [tri-μ-chlorido-chromate(II)]].

Danford James J JJ Arif Atta M AM Berreau Lisa M LM

Acta crystallographica. Section E, Structure reports online 20090128 Pt 2

The title compound, {(C(6)H(11)N(2))[CrCl(3)]}(n), was generated via mixing of the ionic liquid 1-ethyl-3-methyl-imidazolium chloride with CrCl(2) in ethanol. Crystals were obtained by a diffusion method. In the crystal structure, the anion forms one-dimensional chains of chloride-bridged Jahn-Teller distorted chromium(II) centers extending along the [100] direction. The imidazolium cations are positioned between these chains. ...[more]

PMID: 21581818

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