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Tri-?-chlorido-bis-[(?-hexa-methyl-benzene)-ruthenium(II)] tetra-chlorido-ferrate(III).

ABSTRACT: The mol-ecular geometry of the complex cation in the title structure, [(?-Cl)(3){Ru(II)(?(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ?). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891?(7)-2.2018?(8)?Å and 107.10?(3)-110.56?(3)°, respectively. There are no significant inter-molecular inter-actions in the crystal except for some weak C-H?Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic inter-actions between the ionic constituents.

SUBMITTER: Stepnicka P 

PROVIDER: S-EPMC3201229 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Tri-μ-chlorido-bis-[(η-hexa-methyl-benzene)-ruthenium(II)] tetra-chlorido-ferrate(III).

Stěpnička Petr P   Schulz Jiří J   Císařová Ivana I  

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The mol-ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ▶). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891 (7)-2.2018 (8) Å and 107.10 (3)-110.56 (3)°, respectively. There are no significant inter-molecular i  ...[more]

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