Unknown

Dataset Information

0

Tri-?-chlorido-bis-[(?-hexa-methyl-benzene)-ruthenium(II)] tetra-chlorido-ferrate(III).

ABSTRACT: The mol-ecular geometry of the complex cation in the title structure, [(?-Cl)(3){Ru(II)(?(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ?). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891?(7)-2.2018?(8)?Å and 107.10?(3)-110.56?(3)°, respectively. There are no significant inter-molecular inter-actions in the crystal except for some weak C-H?Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic inter-actions between the ionic constituents.

SUBMITTER: Stepnicka P 

PROVIDER: S-EPMC3201229 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tri-μ-chlorido-bis-[(η-hexa-methyl-benzene)-ruthenium(II)] tetra-chlorido-ferrate(III).

Stěpnička Petr P   Schulz Jiří J   Císařová Ivana I  

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The mol-ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ▶). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891 (7)-2.2018 (8) Å and 107.10 (3)-110.56 (3)°, respectively. There are no significant inter-molecular i  ...[more]

Similar Datasets

Unknown Di-μ(2)-chlorido-bis-[chlorido(η-hexa-methyl-benzene)ruthenium(II)].
| S-EPMC2971002 | biostudies-literature
Unknown Hexa-?-chlorido-hexa-chlorido(?-hexa-methyl-benzene)trialuminium(III)lanthanum(III) benzene solvate.
| S-EPMC2968558 | biostudies-literature
Unknown Tri-methyl-phospho-nium trans-tetra-chlorido-bis-(tri-methyl-phosphane-κP)iridate(III).
| S-EPMC3998401 | biostudies-literature
Unknown [Bis-(2-pyrid-yl-?N)amine]chlorido(?-hexa-methyl-benzene)-ruthenium(II) hexa-fluorido-phosphate dichloro-methane solvate.
| S-EPMC3089226 | biostudies-literature
Unknown 2-Carbamylpyridinium tetra-chlorido-ferrate(III).
| S-EPMC2970958 | biostudies-literature
Unknown Bis(4,4'-methyl-enedicyclo-hexyl-aminium) μ-benzene-1,4-dicarboxyl-ato-bis-[tri-chlorido-zinc(II)] tetra-hydrate.
| S-EPMC2959686 | biostudies-literature
Unknown Poly[[diaqua-tetra-kis-(μ(2)-benzene-1,4-di-carbonitrile-κN:N')iron(II)] bis-[tetra-chlorido-ferrate(III)] nitro-methane tetra-solvate].
| S-EPMC3274928 | biostudies-literature
Unknown Butyl-triethyl-ammonium tetra-chlorido-ferrate(III).
| S-EPMC3344376 | biostudies-literature
Unknown Tris(2-methyl-piperidinium) tetra-chlorido-ferrate dichloride.
| S-EPMC3344378 | biostudies-literature
Unknown Benzyl-triethyl-ammonium tetra-chlorido-ferrate(III).
| S-EPMC3379130 | biostudies-other