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Hexaaqua-cobalt(II) bis-{[N-(4-meth-oxy-2-oxidobenzyl-idene)glycyl-glycinato]copper(II)} hexa-hydrate.


ABSTRACT: In the crystal structure of the title compound, [Co(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Co(II) atom is located on an inversion center and coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. The Cu(II) atom is chelated by the Schiff base ligand in a distorted CuN(2)O(2) square-planar geometry. An extensive O-H?O hydrogen-bonding network is present in the crystal structure.

SUBMITTER: Yao GB 

PROVIDER: S-EPMC2971010 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Hexaaqua-cobalt(II) bis-{[N-(4-meth-oxy-2-oxidobenzyl-idene)glycyl-glycinato]copper(II)} hexa-hydrate.

Yao Gan-Bing GB   Jiang Jia-Xun JX   Yuan Li-Min LM   Ren Xiao-Ming XM  

Acta crystallographica. Section E, Structure reports online 20091007 Pt 11


In the crystal structure of the title compound, [Co(H(2)O)(6)][Cu(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Co(II) atom is located on an inversion center and coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. The Cu(II) atom is chelated by the Schiff base ligand in a distorted CuN(2)O(2) square-planar geometry. An extensive O-H⋯O hydrogen-bonding network is present in the crystal structure. ...[more]

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