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Catena-Poly[[tetra-aqua-copper(II)]-?-tri-thionato-?O:O'].

ABSTRACT: The title supra-molecular polymer, [Cu(S(3)O(6))(H(2)O)(4)](n), features a tetra-gonally distorted octa-hedral Cu(II) centre within an O(6) donor set with the longer Cu-O bonds linking the dication and the trithio-nate dianion. Extensive O-H?O hydrogen-bonding inter-actions connect the supra-molecular chains into a three-dimensional network.

SUBMITTER: Tiekink ER

PROVIDER: S-EPMC2972059 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[tetra-aqua-copper(II)]-μ-tri-thionato-κO:O'].

Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

The title supra-molecular polymer, [Cu(S(3)O(6))(H(2)O)(4)](n), features a tetra-gonally distorted octa-hedral Cu(II) centre within an O(6) donor set with the longer Cu-O bonds linking the dication and the trithio-nate dianion. Extensive O-H⋯O hydrogen-bonding inter-actions connect the supra-molecular chains into a three-dimensional network. ...[more]

PMID: 21578544

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