Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[6-(4-Bromo-phen-yl)-2,2'-bipyridine-?N,N'](tricyclo-hexyl-phosphine-?P)copper(I) tetra-fluoridoborate.

ABSTRACT: In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromo-phen-yl)-2,2'-bipyridine ligand and a P atom from the tricyclo-hexyl-phosphine ligand. In addition, a weak anion?Cu(I) inter-action with a nearest F?Cu separation of 2.696?(5)?Å is found.

SUBMITTER: Peng XL

PROVIDER: S-EPMC2979668 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[6-(4-Bromo-phen-yl)-2,2'-bipyridine-κN,N'](tricyclo-hexyl-phosphine-κP)copper(I) tetra-fluoridoborate.

Peng Xi-Long XL

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromo-phen-yl)-2,2'-bipyridine ligand and a P atom from the tricyclo-hexyl-phosphine ligand. In addition, a weak anion⋯Cu(I) inter-action with a nearest F⋯Cu separation of 2.696 (5) Å is found. ...[more]

PMID: 21579680

Similar Datasets

[6-(4-Bromo-phen-yl)-2,2'-bipyridine-?N,N']bis-(triphenyl-phosphane-?P)copper(I) tetra-fluoridoborate.

Project description:The title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(15)P)(2)]BF(4), is composed of one Cu(I) atom, one 6-(4-bromo-phen-yl)-2,2'-bipyridine (L) ligand, two triphenyl-phosphane mol-ecules and one tetra-fluoridoborate anion. The Cu(I) ion is four-coordinated in a distorted tetra-hedral configuration by two N atoms from L and two P atoms from triphenyl-phosphane ligands. In the L ligand, the two pyridine rings are not coplanar; the mean planes making a dihedral angle of 15.3?(5)°. In the crystal, the ions are linked by weak C-H?F inter-actions.

| S-EPMC3200642 | biostudies-literature

Aqua-bis(triphenyl-phosphine-?P)copper(I) tetra-fluoridoborate.

Project description:In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl-phosphine ligands and one water mol-ecule in a distorted trigonal geometry. In the BF(4) (-) anion, three F atoms are disordered over two sites around the B-F bond, the site-occupancy ratio being 0.67?(6):0.33?(6). The Cu?F distance of 2.602?(5)?Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter-action. O-H?F and weak C-H?F hydrogen bonding is present in the crystal structure.

| S-EPMC2977191 | biostudies-literature

Bis(pyridine-?N)bis-(triphenyl-phosphine-?P)copper(I) tetra-fluoridoborate.

Project description:The title compound, [Cu(C(5)H(5)N)(2)(C(18)H(15)P)(2)]BF(4), crystallizes as discrete [(PPh(3))(2)(py)(2)Cu](+) cations and [BF(4)](-) anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C-H?F inter-actions apparent. The P(2)CuN(2) coordination geometry is pseudo-tetra-hedral, with P-Cu-P and N-Cu-N angles of 116.02?(6) and 101.5?(2)°, respectively.

| S-EPMC2961139 | biostudies-literature

cis-Bis(acetonitrile-?N)bis-(2,2'-bipyridine-?N,N')ruthenium(II) tetra-fluoridoborate.

Project description:In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa-hedral geometry by the N atoms of the two 2,2'-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol-ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86?(12) and 10.12?(14)°. In the crystal, the cations and anions are linked by C-H?F hydrogen bonds into a three-dimensional network.

| S-EPMC3254331 | biostudies-literature

1-Bromo-2,4,6-tricyclo-hexyl-benzene.

Project description:The title compound, C(24)H(25)Br, packs efficiently in the crystal structure with no solvent-accessible voids and several inter-molecular H?H contacts approximating the sum of the van der Waals radii. The mol-ecule is quite crowded, with intra-molecular Br?H and C?H contacts ca 0.38 and 0.30?Å, respectively, less than the sum of the corresponding van der Waals radii. All cyclo-hexyl rings adopt chair conformations with the 'seat' of the chair inclined at approximately 57-81° to the mean plane of the benzene ring, while those ortho to bromine have their centroids displaced in opposite directions from this plane.

| S-EPMC2915376 | biostudies-literature

Tetra-aqua(2,2'-bipyridine-?N,N')magnesium(II) bis-(4-bromo-benzoate).

Project description:In the complex cation of the title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)BrO(2))(2), the Mg(II) atom is coordinated by two N atoms from a 2,2'-bipyridine ligand and four water O atoms in a distorted MgN(2)O(4) octa-hedral geometry. The cation is located on a special position on a twofold rotation axis which passes through the Mg(II) atom and the centroid of the 2,2'-bipyridine ligand. The 2,2'-bipyridine ligands exhibit nearly perfect coplanarity (r.m.s. deviation = 0.0035?Å) . In the crystal, O-H?O and C-H?O, C-H?Br hydrogen bonds and ?-? stacking inter-actions [mean inter-planar distance of 3.475?(6)?Å between adjacent 2,2'-bipyridine ligands] link the cations and anions into a three-dimensional supra-molecular network. One Br atom is disordered over two sites with occupancy factors of 0.55 and 0.45.

| S-EPMC3009127 | biostudies-literature

[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62?(5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970?(5)?Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.

| S-EPMC2979177 | biostudies-literature

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10?(5) and 177.26?(5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au?O contacts = 3.054?(4) and 3.013?(4)?Å, respectively, for the two mol-ecules].

| S-EPMC2983779 | biostudies-literature

Tricarbonyl-bis(tricyclo-hexyl-phosphine-?P)ruthenium(0) toluene solvate.

Project description:The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol-ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C-Ru-C bond angle [127.5?(3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo-hexyl).

| S-EPMC2959764 | biostudies-literature

(Triphenyl-phosphine-κP)[1,1,1-tris-(diphenyl-phosphinometh-yl)ethane-κP,P',P'']copper(I) tetra-fluoridoborate.

Project description:In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra-hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two positions, with an occupancy ratio of 0.524 (17):0.476 (17). The cations and anions are closely packed in the crystal and are in h.c.p. arrangements.

| S-EPMC2983927 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data