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(+)-[1-(4-Methoxy-benz-yl)pyrrolidin-2-yl]diphenyl-methanol.


ABSTRACT: The title compound, C(25)H(27)NO(2), was obtained as the product of a Grignard reagent and an inter-mediate ester synthesized from L-(-)-proline. The asymmetric unit contains two independent mol-ecules, both of which feature an intra-molecular O-H?N hydrogen bond. In one of the mol-ecules, the pyrrolidine ring is disordered over two orientations in a 0.63?(3):0.37?(3) ratio.

SUBMITTER: Jin J 

PROVIDER: S-EPMC2977718 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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(+)-[1-(4-Methoxy-benz-yl)pyrrolidin-2-yl]diphenyl-methanol.

Jin Jia J   Xue Si-Jia SJ   Li Xue-Fei XF   Fang Zhi-Kun ZK  

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5


The title compound, C(25)H(27)NO(2), was obtained as the product of a Grignard reagent and an inter-mediate ester synthesized from L-(-)-proline. The asymmetric unit contains two independent mol-ecules, both of which feature an intra-molecular O-H⋯N hydrogen bond. In one of the mol-ecules, the pyrrolidine ring is disordered over two orientations in a 0.63 (3):0.37 (3) ratio. ...[more]

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