Browse
Submit Data
Databases
API
Help

Dataset Information

15 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichloridobis(1,3-phenyl-propane-1,3-dionato-?O,O')tin(IV) toluene hemisolvate.

ABSTRACT: The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626?(1)?Å in one ring and by 0.690?(1)?Å for the other. The two planes are aligned at an angle of 59.6?(1)°. The Cl atoms occupy cis positions in the octa-hedral SnCl(2)O(4) coordination environment. The solvent mol-ecule is disordered about a center of inversion.

SUBMITTER: Thy CK

PROVIDER: S-EPMC3007579 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichloridobis(1,3-phenyl-propane-1,3-dionato-κO,O')tin(IV) toluene hemisolvate.

Thy Chun Keng CK Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]·0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octa-hedral SnCl(2)O(4) coordination environment. The solvent mol-ecule is disordered about a center of inversion. ...[more]

PMID: 21588212

Similar Datasets

Tetra-kis(1,3-diphenyl-propane-1,3-dionato)hafnium(IV).

Project description:In the title compound, [Hf(C(15)H(11)O(2))(4)], the Hf(IV) atom is coordinated by four 1,3-diphenyl-propane-1,3-dionato ligands with an average Hf-O distance of 2.17?(3)?Å and O-Hf-O bite angles varying from 74.5?(1) to 75.02?(9)°. The coordination polyhedron shows a slightly distorted Archimedean square-anti-prismatic geometry. The crystal packing is stabilized by weak C-H?O inter-actions.

| S-EPMC3008122 | biostudies-literature

trans-Bis(1,3-diphenyl-propane-1,3-dionato)(methanol)oxidovanadium(IV) methanol disolvate.

Project description:In the title compound, [V(C15H11O2)2O(CH3OH)]·2CH3OH, the V(IV) atom is coordinated by two 1,3-diphenyl-propane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octa-hedral geometry is significantly distorted, with the V(IV) atom lying 0.330?(3)?Å above the equatorial plane formed by the O atoms of the two ?-diketonate ligands. In the crystal, O-H?O hydrogen bonds between the coordinating methanol group in the complex and the two methanol solvent mol-ecules lead to the formation of polymeric chains along the c-axis direction. Weak C-H?O contacts are also observed.

| S-EPMC3588710 | biostudies-literature

Dichloridobis(2-chloro-benz-yl)tin(IV).

Project description:Mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)], lie on a twofold rotation axis which passes through the Sn atom. The Sn(IV) atom exists in a distorted tetra-hedral geometry. Adjacent mol-ecules are linked by weak Sn?Cl contacts [3.703?(1)?Å], forming a linear chain motif extending along the b axis.

| S-EPMC3007463 | biostudies-literature

Poly[tetra-kis[?(2)-1,3-bis-(4-pyrid-yl)propane-?N:N']dichloridobis(phenyl-acetato)dimanganese(II)].

Project description:In the title compound, [Mn(2)(C(8)H(7)O(2))(2)Cl(2)(C(13)H(14)N(2))(4)](n), the two Mn(II) atoms lie on inversion centers and are connected by the N-heterocyclic ligands into a wave-like lamellar framework structure. One Mn(II) atom is covalently bonded to two Cl atoms and the other to two benzyl-acetate anions; both Mn atoms show distorted octahedral coordinations.

| S-EPMC2983499 | biostudies-literature

trans-Dichloridobis(propane-1,3-diamine-κN,N')chromium(III) perchlorate.

Project description:In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)]ClO(4), the Cr(III) atom is coordinated equatorially by four N atoms of two propane-1,3-diamine (tn) ligands and axially by two mutually trans Cl atoms, thus displaying a slightly distorted octa-hedral geometry with no crystallographically imposed symmetry. The two six-membered chair chelate rings in the complex cation are in an anti conformation with respect to each other. The Cr-N bond lengths range from 2.0831 (18) to 2.0917 (19) Å, and the Cr-Cl bond lengths are 2.3148 (6) and 2.3135 (6) Å. The perchlorate anions have slightly distorted tetra-hedral geometries. Weak inter-molecular hydrogen bonds involving the tn ligand NH groups as donors, and chloride ligands and anion O atoms as acceptors are observed.

| S-EPMC3052098 | biostudies-literature

Dichloridobis(2-methyl-quinolin-8-olato-?N,O)tin(IV).

Project description:The bis-chelated Sn atom in the title compound, [Sn(C(10)H(8)NO)(2)Cl(2)], exists in a distorted cis-Cl(2),cis-N(2),trans-O(2) octa-hedral environment.

| S-EPMC2969261 | biostudies-literature

Dichloridobis(pyridine-2-seleno-lato-?(2) N,Se)tin(IV).

Project description:The title compound, [SnCl2(C5H4NSe)2], is the product of a reaction of 2,2'-dipyridyl diselenide with tin tetra-chloride. The mol-ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa-hedron, with two bidentate 2-pyridine-seleno-late ligands inclined to each other at an angle of 83.96?(7)°. The two Sn-Cl and two Sn-N bonds are in cis configurations, while the two Sn-Se bonds of 2.5917?(3)?Å are in a trans configuration, with an Se-Sn-Se angle of 157.988?(15)°. In the crystal, ?-? inter-actions between the pyridine rings [centroid-to-centroid distance of 3.758?(3)?Å] and weak inter-molecular C-H?Cl hydrogen bonds link the mol-ecules into chains along the c axis.

| S-EPMC3772407 | biostudies-literature

Dichloridobis(5,7-dichloro-quinolin-8-olato-?N,O)tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(9)H(4)Cl(2)NO)(2)Cl(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the Cl atoms; the O atoms are trans to each other.

| S-EPMC2968467 | biostudies-literature

Bis[2-(1,3-benzo-thia-zol-2-yl)phenyl-?(2) C (1),N][1,3-bis-(4-bromo-phen-yl)propane-1,3-dionato-?(2) O,O']iridium(III).

Project description:The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis-(bromo-phen-yl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octa-hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia-zole ring systems in the complex is 77.45?(10)°.

| S-EPMC3793684 | biostudies-literature

Tri-phenyl-telluronium(IV) bromide acetone hemisolvate.

Project description:The asymmetric unit of the title compound, 2C18H15Te(+)·2Br(-)·C3H6O or Ph3TeBr·0.5Me2CO, contains two crystallographically independent tri-phenyl-telluronium cations, two bromide anions, and one disordered [site-occupancy ratio = 0.581?(7):0.419?(7)] solvent mol-ecule. Inter-ionic Te?Br inter-actions connect the cations and anions into a tetra-meric step-like structure. The primary coordination spheres of both Te atoms are TeC3 trigonal pyramids: three short secondary tellurium-bromine inter-actions expand the coordination geometry of one of the Te atoms to an octa-hedron. While the other Te atom shows only two Te?Br secondary bonding inter-actions, it is also six-coordinated due to a Te?? inter-action [3.769?(2)?Å] with one of the phenyl rings of the adjacent cation.

| S-EPMC3884325 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data