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Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate.

ABSTRACT: The title compound, C(36)H(30)NP(2) (+)·Br(-)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P-N-P angle [142.88?(10)°] is significantly larger than in the corresponding chloride and iodide structures.

SUBMITTER: Knapp C 

PROVIDER: S-EPMC3011659 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate.

Knapp Carsten C   Uzun Rabiya R  

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12

The title compound, C(36)H(30)NP(2) (+)·Br(-)·C(2)H(3)N, crystallized from a CH(3)CN/OEt(2) solution as an acetonitrile solvate. The central P-N-P angle [142.88 (10)°] is significantly larger than in the corresponding chloride and iodide structures. ...[more]

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