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Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II).

ABSTRACT: In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C-H?N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.

SUBMITTER: Rowthu SR

PROVIDER: S-EPMC3152144 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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Diazido-{(S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine}-copper(II).

Rowthu Sankara Rao SR Shin Jong Won JW Kim Seung-Hui SH Kim Jong Jin JJ Min Kil Sik KS

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the title compound, [Cu(N(3))(2)(C(20)H(21)N(3))], the Cu(II) ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis-[(2-pyrid-yl)meth-yl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak inter-molecular C-H⋯N hydrogen-bonding inter-action between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis. ...[more]

PMID: 21836869

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