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Bis(acetato-?O)bis-(2-pyridine-aldoxime-?(2)N,N')cadmium.

ABSTRACT: In the title mol-ecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N'-chelated by two 2-pyridine-aldoxime ligands and coordinated by two acetate anions in a distorted octa-hedral geometry. The hy-droxy groups of the 2-pyridine-aldoxime ligands link to the acetate anions via intra-molecular O-H?O hydrogen bonds. Weak inter-molecular C-H?O hydrogen bonds occur in the crystal.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3414138 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Bis(acetato-κO)bis-(2-pyridine-aldoxime-κ(2)N,N')cadmium.

Shirvan Sadif A SA Haydari Dezfuli Sara S

Acta crystallographica. Section E, Structure reports online 20120718 Pt 8

In the title mol-ecule, [Cd(CH(3)COO)(2)(C(6)H(6)N(2)O)(2)], the Cd(II) cation is N,N'-chelated by two 2-pyridine-aldoxime ligands and coordinated by two acetate anions in a distorted octa-hedral geometry. The hy-droxy groups of the 2-pyridine-aldoxime ligands link to the acetate anions via intra-molecular O-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯O hydrogen bonds occur in the crystal. ...[more]

PMID: 22904745

Similar Datasets

Bis(acetato-?O)bis-(pyridine-2-aldoxime-?(2)N,N')nickel(II).

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Tetra-pyridine-bis(trichloro-acetato)nickel(II).

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Crystal structure of bis-(acetato-?O)bis-(pyridine-2-carboxamide oxime-?(2) N,N')cadmium ethanol disolvate.

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Bis(acetato-?O,O')bis-[4-(dimethyl-amino)-pyridine-?N]copper(II).

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Project description:In the structure of the title compound, [Cd(C(9)H(7)N(2)O(2)S)(2)(C(10)H(8)N(2))(2)], the complex mol-ecules are located on a crystallographic twofold rotation axis and the Cd(II) ion is octa-hedrally coordinated by two chelating 2,2'-bipyridine ligands and two O atoms from the carboxyl-ate groups of two 2-(benzimidazol-2-ylsulfan-yl)acetate ligands. The two carboxyl-ate ligands adopt a cis configuration with respect to each other. Within each of these ligands, the imidazole fragments are bent back in a loop towards the acetyl groups, forming intra-molecular N-H?O hydrogen bonds, which help to stablilize the mononuclear complex. Adjacent mol-ecules are further linked by weak C-H?O hydrogen bonds, resulting in a chain along the c axis.

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Poly[[bis-[?-1,2-bis-(4-pyrid-yl)ethene]bis-(trichloro-acetato)-cadmium(II)] monohydrate].

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Tetra-?-acetato-bis-[(pyridine N-oxide)copper(II)](Cu-Cu).

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