Unknown

Dataset Information

0

Catena-Poly[[chlorido[1-(3-nitro-phen-yl)-2-(triphenyl-phospho-ranyl-idene)ethanone-?C(2)]mercury(II)]-?-chlorido].

ABSTRACT: In the title organometallic polymer, [HgCl(2)(C(26)H(20)NO(3)P)](n), the monodentate 1-(3-nitro-phen-yl)-2-(triphenyl-phospho-ran-yl--idene)ethanone ligand is coordinated to the Hg(II) atom through the methine C atom. The Hg(II) atom is four-coordinated in a distorted tetra-hedral geometry by one terminal Cl atom, two bridging Cl atoms, and one C atom from the ylidic ligand, resulting in a polymeric chain parallel to [010]. The terminal Cl atom is more strongly bound to the Hg(II) ion [2.3916?(9)?Å] than the bridging Cl atoms. The bridge is asymmetric, as indicated by the two different Hg-Cl(bridging) bond lengths [2.5840?(8) and 2.7876?(8)?Å]. Intra-molecular C-H?O and weak C-H?Cl contacts stabilize the polymeric chain. In the crystal, adjacent chains inter-act via C-H?O hydrogen bonds.

SUBMITTER: Dadrass A 

PROVIDER: S-EPMC3515143 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[chlorido[1-(3-nitro-phen-yl)-2-(triphenyl-phospho-ranyl-idene)ethanone-κC(2)]mercury(II)]-μ-chlorido].

Dadrass Alireza A   Khalafy Jabbar J   Rahchamani Hojjatollah H   Nasri Koureh Hassan H   Yaghoobnejad Asl Hooman H  

Acta crystallographica. Section E, Structure reports online 20121024 Pt 11

In the title organometallic polymer, [HgCl(2)(C(26)H(20)NO(3)P)](n), the monodentate 1-(3-nitro-phen-yl)-2-(triphenyl-phospho-ran-yl--idene)ethanone ligand is coordinated to the Hg(II) atom through the methine C atom. The Hg(II) atom is four-coordinated in a distorted tetra-hedral geometry by one terminal Cl atom, two bridging Cl atoms, and one C atom from the ylidic ligand, resulting in a polymeric chain parallel to [010]. The terminal Cl atom is more strongly bound to the Hg(II) ion [2.3916 (9  ...[more]

Similar Datasets

Unknown 4-Acetamido-N-(?-triphenyl-phospho-ranyl-idene)benzene-sulfonamide.
| S-EPMC2979042 | biostudies-literature
Unknown Bis(triphenyl-phospho-ranyl-idene)ammonium iodide.
| S-EPMC2979852 | biostudies-other
Unknown Trimethyl-3-meth-oxy-4-oxo-5-triphenyl-phospho-ranyl-idene-cyclo-pent-1-ene-1,2,3-tricarboxyl-ate.
| S-EPMC3009217 | biostudies-literature
Unknown 2-[(2Z)-Azepan-2-yl-idene]-1-(4-nitro-phen-yl)ethanone.
| S-EPMC3414934 | biostudies-literature
Unknown Chlorido[1-(2-eth-oxy-phen-yl)3-(4-nitro-phen-yl)triazenido]mercury(II).
| S-EPMC3007569 | biostudies-literature
Unknown Di-μ-chlorido-bis-{chlorido[4-nitro-N-(pyridin-2-yl-methyl-idene-κN)aniline-κN]mercury(II)}.
| S-EPMC3051965 | biostudies-literature
Unknown catena-Poly[[chlorido(methyl phenyl sulfide-?S)mercury(II)]-?-chlorido].
| S-EPMC2961523 | biostudies-literature
Unknown (m-Phenyl-enedimethyl-ene)bis-(triphenyl-phospho-nium) bis-[chlorido(penta-fluoro-phen-yl)aurate(I)] dichloro-methane disolvate.
| S-EPMC2971990 | biostudies-literature
Unknown 2-Bromo-1-(3-nitro-phen-yl)ethanone.
| S-EPMC3050415 | biostudies-literature
Unknown 2-Azido-1-(4-nitro-phen-yl)ethanone.
| S-EPMC3379503 | biostudies-literature