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[4-(Dimethyl-amino)-pyridine-?N(1)]tri-methyl(thio-cyanato-?N)tin(IV).

ABSTRACT: In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033?(4)?Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8?(2)%.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3379119 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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[4-(Dimethyl-amino)-pyridine-κN(1)]tri-methyl(thio-cyanato-κN)tin(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%. ...[more]

PMID: 22719340

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