Ontology highlight
ABSTRACT:
SUBMITTER: Bats JW
PROVIDER: S-EPMC2959829 | biostudies-other | 2008
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20081129 Pt 12
The absolute configuration of the title mol-ecule, [Fe(C(5)H(5))(C(38)H(34)NP(2))]·CHCl(3), is R,R(p). The mol-ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007 ▶). J. Org. Chem. 72, 1514-1517], but some torsion angles about the P-C(phen-yl) bonds differ by up to 25°. The P atoms and the N atom have a distorted trigonal-pyramidal geometry. The chloro-form solvate group donates a C-H⋯π bond to the central benzene ring and is also involve ...[more]