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Diaqua-bis[5-(2-pyrid-yl)tetra-zolato-?N,N]iron(II).

ABSTRACT: The title complex, [Fe(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the reaction of ferrous sulfate with 5-(2-pyrid-yl)-2H-tetra-zole (HL). The Fe(II) atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water mol-ecules in a distorted octa-hedral geometry. The Fe(II) mononuclear units are further connected by inter-molecular O-H?N and C-H?O hydrogen-bonding inter-actions, forming a three-dimensional framework.

SUBMITTER: Hu M 

PROVIDER: S-EPMC2968821 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Diaqua-bis[5-(2-pyrid-yl)tetra-zolato-κN,N]iron(II).

Hu Min M   Ma Song-Tao ST   Guo Liang-Qi LQ   Fang Shao-Ming SM  

Acta crystallographica. Section E, Structure reports online 20090311 Pt 4

The title complex, [Fe(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the reaction of ferrous sulfate with 5-(2-pyrid-yl)-2H-tetra-zole (HL). The Fe(II) atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water mol-ecules in a distorted octa-hedral geometry. The Fe(II) mononuclear units are further connected by inter-molecular O-H⋯N and C-H⋯O hydrogen-bonding inter-actio  ...[more]

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