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[1,1'-Bis(diphenyl-phosphino)cobalto-cenium-?P,P']dichloridoplatinum(II) hexa-fluorido-phosphate.

ABSTRACT: The title bimetallic compound, [PtCl(2){Co(C(17)H(14)P)(2)}]PF(6), was obtained by reaction of 1,1'-bis-(diphenyl-phosphino)cobalto-cenium hexa-fluorido-phosphate with bis-(acetonitrile)di-chloridoplatinum. The Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1'-bis-(diphenyl-phosphino)cobaltocenium moiety and two Cl atoms. In the crystal structure, mol-ecules are linked by weak C-H?F and C-H?Cl hydrogen bonds.

SUBMITTER: Guan JT

PROVIDER: S-EPMC2977235 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[1,1'-Bis(diphenyl-phosphino)cobalto-cenium-κP,P']dichloridoplatinum(II) hexa-fluorido-phosphate.

Guan Jin-Tao JT Zhang Kai-Cheng KC Dai Zhi-Qun ZQ

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8

The title bimetallic compound, [PtCl(2){Co(C(17)H(14)P)(2)}]PF(6), was obtained by reaction of 1,1'-bis-(diphenyl-phosphino)cobalto-cenium hexa-fluorido-phosphate with bis-(acetonitrile)di-chloridoplatinum. The Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1'-bis-(diphenyl-phosphino)cobaltocenium moiety and two Cl atoms. In the crystal structure, mol-ecules are linked by weak C-H⋯F and C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21583406

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