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Poly[diaqua-tris(?(4)-isophthalato)dilanthanum(III)].

ABSTRACT: In the title coordination polymer, [La(2)(C(8)H(4)O(4))(3)(H(2)O)(2)](n), there are two independent La(III) atoms which are coordinated differently in slightly distorted penta-gonal-bipyramidal and slightly disorted bicapped trigonal-prismatic environments. The La(III) ions are bridged by ?(4)-isophthalate ligands, forming two-dimensional layers. In the crystal structure, these layers are connected by inter-molecular O-H?O hydrogen bonds into a three-dimensional network.

SUBMITTER: Fan LQ

PROVIDER: S-EPMC2979801 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Poly[diaqua-tris(μ(4)-isophthalato)dilanthanum(III)].

Fan Le-Qing LQ Wu Ji-Huai JH

Acta crystallographica. Section E, Structure reports online 20100130 Pt 2

In the title coordination polymer, [La(2)(C(8)H(4)O(4))(3)(H(2)O)(2)](n), there are two independent La(III) atoms which are coordinated differently in slightly distorted penta-gonal-bipyramidal and slightly disorted bicapped trigonal-prismatic environments. The La(III) ions are bridged by μ(4)-isophthalate ligands, forming two-dimensional layers. In the crystal structure, these layers are connected by inter-molecular O-H⋯O hydrogen bonds into a three-dimensional network. ...[more]

PMID: 21579693

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