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Crystal structure of aqua-chlorido-bis-(2-eth-oxy-6-formyl-phenolato-?(2) O (1),O (6))iron(III) aceto-nitrile hemisolvate.

ABSTRACT: In the title compound, [Fe(L)2Cl(H2O)]·0.5CH3CN, (HL is 3-eth-oxy-2-hy-droxy-benzaldehyde, C9H10O3), there are two independent complex mol-ecules and one aceto-nitrile solvent mol-ecule in the asymmetric unit. In each complex mol-ecule, the Fe(III) ion has a distorted O5Cl octa-hedral coordination environment defined by two bidentate 2-eth-oxy-6-formyl-phenolato ligands, one Cl atom and one water mol-ecule. In the crystal, O-H?O hydrogen bonds link the two independent mol-ecules to form a dimer. The solvent mol-ecule is linked to the complex mol-ecule by a weak C-H?O hydrogen bond. Further weak C-H?O inter-actions along with weak C-H?Cl hydrogen bonds link the components into chains parallel to [001].

SUBMITTER: Jiang XF

PROVIDER: S-EPMC4257307 | biostudies-other | 2014 Nov

REPOSITORIES: biostudies-other

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Crystal structure of aqua-chlorido-bis-(2-eth-oxy-6-formyl-phenolato-κ(2) O (1),O (6))iron(III) aceto-nitrile hemisolvate.

Jiang Xi-Fu XF Zhao Ru-Xia RX Zhang Shu-Hua SH

Acta crystallographica. Section E, Structure reports online 20141004 Pt 11

In the title compound, [Fe(L)2Cl(H2O)]·0.5CH3CN, (HL is 3-eth-oxy-2-hy-droxy-benzaldehyde, C9H10O3), there are two independent complex mol-ecules and one aceto-nitrile solvent mol-ecule in the asymmetric unit. In each complex mol-ecule, the Fe(III) ion has a distorted O5Cl octa-hedral coordination environment defined by two bidentate 2-eth-oxy-6-formyl-phenolato ligands, one Cl atom and one water mol-ecule. In the crystal, O-H⋯O hydrogen bonds link the two independent mol-ecules to form a dimer. ...[more]

PMID: 25484720

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