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Crystal structure of trans-di-chlorido-(4-nitro-aniline-?N (1))(piperidine-?N)platinum(II).

ABSTRACT: In the title complex, [PtCl2(C5H11N)(C6H6N2O2)], the Pt(II) metal atom displays a slightly distorted trans-PtN2Cl2 square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03?(3)°. In the crystal structure, inversion dimers are formed via N-H?Cl hydrogen-bond inter-actions, resulting in chains parallel to the [001] direction. The benzene rings within the chains show ?-? stacking inter-actions [centroid-to-centroid distances of 3.801?(3)?Å] and neighbouring chains inter-act via N-H?O hydrogen bonds.

SUBMITTER: Nguyen Thi Thanh C

PROVIDER: S-EPMC4459372 | biostudies-other | 2015 Jun

REPOSITORIES: biostudies-other

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Crystal structure of trans-di-chlorido-(4-nitro-aniline-κN (1))(piperidine-κN)platinum(II).

Nguyen Thi Thanh Chi C Hoang Van Truong T Pham Van Thong T Nguyen Bich Ngan N Van Meervelt Luc L

Acta crystallographica. Section E, Crystallographic communications 20150520 Pt 6

In the title complex, [PtCl2(C5H11N)(C6H6N2O2)], the Pt(II) metal atom displays a slightly distorted trans-PtN2Cl2 square-planar coordination geometry. The dihedral angle between the mean plane of the benzene and piperidine rings is 89.03 (3)°. In the crystal structure, inversion dimers are formed via N-H⋯Cl hydrogen-bond inter-actions, resulting in chains parallel to the [001] direction. The benzene rings within the chains show π-π stacking inter-actions [centroid-to-centroid distances of 3.801 ...[more]

PMID: 26090140

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