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Poly[bis-(?(2)-benzyl-oxyacetato-?O,O':O'')cadmium(II)].

ABSTRACT: The title cadmium derivative of benzyl-oxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a ?(2)-carboxyl-ate-bridged layer network. Two benzyl-oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl-oxyacetate units in an octa-hedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions.

SUBMITTER: Liu JW

PROVIDER: S-EPMC2961155 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Poly[bis-(μ(2)-benzyl-oxyacetato-κO,O':O'')cadmium(II)].

Liu Ji-Wei JW Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5

The title cadmium derivative of benzyl-oxyacetic acid, [Cd(C(9)H(9)O(3))(2)](n), exists as a μ(2)-carboxyl-ate-bridged layer network. Two benzyl-oxyacetate units each chelate the metal through a carboxylate as well as through the ether O atoms; the metal is also coordinated by the double-bond carbonyl O atom of two adjacent benzyl-oxyacetate units in an octa-hedral geometry. The metal atom lies on a special position of 2 site symmetry. The phenyl group is disordered equally over two positions. ...[more]

PMID: 21202238

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