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Trans-Dibromidobis(tri-p-tolyl-arsine)palladium(II).

ABSTRACT: In the title compound, [PdBr(2)(C(21)H(21)As)(2)], the Pd(II) ion, residing on a centre of symmetry, is coordinated by two As donor atoms [Pd-As = 2.4276?(2)?Å] and two Br anions [Pd-Br = 2.4194?(2)?Å] in a distorted square-planar geometry [Br-Pd-As = 87.786?(7)°]. A weak intra-molecular C-H?Br inter-action occurs. In the crystal structure, inter-molecular C-H?Br inter-actions are observed.

SUBMITTER: Kirsten L

PROVIDER: S-EPMC2971051 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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trans-Dibromidobis(tri-p-tolyl-arsine)palladium(II).

Kirsten Leo L Steyl Gideon G Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11

In the title compound, [PdBr(2)(C(21)H(21)As)(2)], the Pd(II) ion, residing on a centre of symmetry, is coordinated by two As donor atoms [Pd-As = 2.4276 (2) Å] and two Br anions [Pd-Br = 2.4194 (2) Å] in a distorted square-planar geometry [Br-Pd-As = 87.786 (7)°]. A weak intra-molecular C-H⋯Br inter-action occurs. In the crystal structure, inter-molecular C-H⋯Br inter-actions are observed. ...[more]

PMID: 21578178

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