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[(Z)-O-Isopropyl N-phenyl-thio-car-bam-ato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

ABSTRACT: The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2983967 | biostudies-literature |

REPOSITORIES: biostudies-literature

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[(Z)-N,O-Disopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:In the title compound, [Au(C(7)H(14)NOS)(C(18)H(33)P)], the Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.94 (2)°], with the distortion due to a short intra-molecular Au⋯O contact [2.908 (2) Å].

| S-EPMC2971935 | biostudies-literature

[(Z)-Ethyl N-isopropyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.023?(4)?Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618?(15):0.382?(15) ratio.

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Tricarbonyl-bis(tricyclo-hexyl-phosphine-κP)ruthenium(0) toluene solvate.

Project description:The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol-ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C-Ru-C bond angle [127.5 (3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo-hexyl).

| S-EPMC2959764 | biostudies-literature

[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.060?(3)?Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H??.

| S-EPMC2983763 | biostudies-literature

Tricyclo-hexyl(piperidine-1-dithio-carboxyl-ato-κS)tin(IV).

Project description:In the title compound, [Sn(C(6)H(11))(3)(C(6)H(10)NS(2))], the Sn(IV) atom is tetra-coordinated by three C atoms from cyclo-hexyl groups and one S atom from a piperidine-dithio-carboxyl-ate anion. The coordination geometry is distorted tetra-hedral, with Sn-C bond lengths in the range 2.133 (6)-2.188 (6) Å and with an Sn-S bond length of 2.4516 (19) Å. The nonbonded S atom of the piperidine-dithio-carboxyl-ate anion makes an Sn⋯S contact of 3.174 (3) Å.

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[O-Ethyl N-(4-nitro-phen-yl)thio-carbam-ato-κS](tri-p-tolyl-phosphine-κP)gold(I).

Project description:A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].

| S-EPMC2959883 | biostudies-literature

Chlorido(ethyl-diphenyl-phosphine-κP)(1-pyrrolidinecarbodithio-ato-κS,S')nickel(II).

Project description:In the crystal structure of the title complex, [Ni(C(5)H(8)NS(2))Cl(C(14)H(15)P)], the Ni atom is coordinated by an S,S'-chelating dithio-carbamate, a chloride and a diphenyl-ethyl-phosphine ligand in a distorted square-planar arrangement.

| S-EPMC2961319 | biostudies-literature

[2-(Diphenyl-phosphan-yl)benzene-thiol-ato-κP,S](pyridine-2-thiol-ato-κS)(triphenyl-phosphine-κP)palladium(II).

Project description:In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H⋯π and π-π inter-actions are observed. The pyridyl ring is equally disordered over two positions.

| S-EPMC3008042 | biostudies-literature

trans-Bis(4-methoxy-thio-phenolato-κS)bis-(trimethyl-phosphine-κP)nickel(II).

Project description:The title compound, [Ni(C(7)H(7)OS)(2)(C(3)H(9)P)(2)], was obtained as a product of the reaction of [NiMe(2)(PMe(3))(3)] with two molar equivalents of 4-methoxy-thio-phenol in diethyl ether. The compound is stable in the air for several hours, but rapidly decomposes at room temperature in solution. The Ni atom displays a square-planar coordination with two P-donor atoms lying in trans positions. The benzene rings of the thio-phenolate ligands are almost perpendicular to the square coordination plane, making dihedral angles of 80.43 (4) and 72.60 (4)°.

| S-EPMC2960343 | biostudies-literature

[(Z)-O-Isopropyl N-(4-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.134?(3)?Å].

| S-EPMC2983867 | biostudies-other

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