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[(Z)-O-Isopropyl N-phenyl-thio-car-bam-ato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

ABSTRACT: The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2983967 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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[(Z)-O-Isopropyl N-phenyl-thio-car-bam-ato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100320 Pt 4

The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions. ...[more]

PMID: 21580525

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[(Z)-Ethyl N-isopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.

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[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H⋯π.

| S-EPMC2983763 | biostudies-literature

[(Z)-O-Isopropyl N-(4-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.134 (3) Å].

| S-EPMC2983867 | biostudies-literature

[(Z)-N,O-Disopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:In the title compound, [Au(C(7)H(14)NOS)(C(18)H(33)P)], the Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.94 (2)°], with the distortion due to a short intra-molecular Au⋯O contact [2.908 (2) Å].

| S-EPMC2971935 | biostudies-literature

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au⋯O contacts = 3.054 (4) and 3.013 (4) Å, respectively, for the two mol-ecules].

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[(Z)-O-Ethyl N-phenyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I): a monoclinic polymorph.

Project description:The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P) polymorph [Hall et al. (1993 ▶). Aust. J. Chem.46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43 (3)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.036 (2) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯π inter-actions.

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[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.

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[(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S-Au-P = 177.54 (3)°] can be traced to an intra-molecular Au⋯O contact of 3.009 (3) Å. In the crystal, layers of mol-ecules are stabilized by a combination of C-H⋯O and C-H⋯π inter-actions.

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[(Z)-N-Isopropyl-O-methyl-thio-carbamato-κS](tri-p-tolyl-phosphine-κP)gold(I).

Project description:In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol-ecules comprise the asymmetric unit, and these are connected by an aurophilic inter-action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31 (5) and 176.45 (5)°] ascribed to an intra-molecular Au⋯O contact in each case [2.974 (4) and 3.027 (4) Å].

| S-EPMC2972070 | biostudies-literature

Tricarbonyl-bis(tricyclo-hexyl-phosphine-κP)ruthenium(0) toluene solvate.

Project description:The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol-ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C-Ru-C bond angle [127.5 (3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo-hexyl).

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