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[(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

ABSTRACT: The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14?(5)°] due to the close approach of the O atom to the Au atom [Au?O = 2.882?(3)?Å]. Loosely associated dimers are formed in the crystal structure through C-H?O inter-actions.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2972176 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14 (5)°] due to the close approach of the O atom to the Au atom [Au⋯O = 2.882 (3) Å]. Loosely associated dimers are formed in the crystal structure through C-H⋯O inter-actions. ...[more]

PMID: 21578703

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