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Bis[1,2-bis-(dimethyl-phosphino)-ethane]-dichloridonitro-syltungsten(0) chloride.

ABSTRACT: In the crystal structure of the title compound, [WCl(2)(NO)(C(6)H(16)P(2))(2)]Cl, the seven-coordinated tungsten(II) center displays a distorted penta-gonal-bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4.

SUBMITTER: Avramovic N 

PROVIDER: S-EPMC2915163 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Bis[1,2-bis-(dimethyl-phosphino)-ethane]-dichloridonitro-syltungsten(0) chloride.

Avramović Nataša N   Blacque Olivier O   Schmalle Helmut W HW   Berke Heinz H  

Acta crystallographica. Section E, Structure reports online 20071222 Pt 1

In the crystal structure of the title compound, [WCl(2)(NO)(C(6)H(16)P(2))(2)]Cl, the seven-coordinated tungsten(II) center displays a distorted penta-gonal-bipyramidal geometry with trans nitrosyl and chloride ligands. The NO and Cl ligands are disordered over two positions; the site occupancy factors are 0.6 and 0.4. ...[more]

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