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Bis(N-triisopropyl-silyl-quinolin-8-aminato)nickel(II).

ABSTRACT: The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl-silyl-8-amido-quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol-ecules with the Ni atoms in distorted tetra-hedral environments.

SUBMITTER: Malassa A

PROVIDER: S-EPMC2980055 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Bis(N-triisopropyl-silyl-quinolin-8-aminato)nickel(II).

Malassa Astrid A Jäger Benjamin B Görls Helmar H Westerhausen Matthias M

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1

The reddish-brown title complex, [Ni(C(18)H(27)N(2)Si)(2)], was prepared via the salt-metathesis reaction of N-triisopropyl-silyl-8-amido-quinoline lithium with nickelocene (NiCp(2)). The asymmetric unit contains two symmetry-independent mol-ecules with the Ni atoms in distorted tetra-hedral environments. ...[more]

PMID: 21579956

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