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Catena-Poly[[diacetonitrile-copper(I)]-?-dicyanamido].

ABSTRACT: The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra-hedral coordination sphere. The anionic and neutral ligands lie on different mirror planes (perpendicular to the b and a axis, respectively), while the Cu atom is situated on their inter-section. The asymmetric unit comprises one fourth of the formula unit.

SUBMITTER: Oelkers B

PROVIDER: S-EPMC3238696 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[diacetonitrile-copper(I)]-μ-dicyanamido].

Oelkers Benjamin B Stricker Marion M Sundermeyer Jörg J

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra-hedral coordination sphere. The anionic and neutral ligands lie on different mirror planes (perpendicular to the b and a axis, respectively), while the Cu atom is situated on their inter-section. The asymme ...[more]

PMID: 22199573

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