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Cis-Diiodido(N,N,N',N'-tetra-methyl-ethylenediamine-?(2)N,N')palladium(II).

ABSTRACT: In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N',N'-tetra-methyl-ethylenediamine ligand [Pd-N = 2.125?(3)?Å] and two I atoms [Pd-I = 2.5833?(4)?Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005?Å), imposed by the small bite of the chelating ligand [N-Pd-N angle = 84.68?(18)°].

SUBMITTER: Abellan-Lopez A 

PROVIDER: S-EPMC3414169 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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cis-Diiodido(N,N,N',N'-tetra-methyl-ethylenediamine-κ(2)N,N')palladium(II).

Abellán-López Antonio A   Chicote-Olalla María Teresa MT   Bautista-Cerezo Delia D  

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N',N'-tetra-methyl-ethylenediamine ligand [Pd-N = 2.125 (3) Å] and two I atoms [Pd-I = 2.5833 (4) Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005 Å), imposed by the small bite of the chelating ligand [N-Pd-N angle = 84.68 (18)°]. ...[more]

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