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[1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-?(2) P,P'](?(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-?C}ruthenium(II) hexa-fluorido-phosphate.

ABSTRACT: In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the Ru(II) atom is coordinated by a cyclo-penta-dienyl ring in an ?(5)-mode, one C atom from a 4,4'-diethynyl-1,1'-biphenyl ligand and two P atoms from a chelating 1,1'-bis-(di-phenyl-phosphan-yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C-H?F hydrogen bonds link the complex cations and hexa-fluorido-phosphate anions into a three-dimensional supra-molecular structure.

SUBMITTER: Zeng LZ

PROVIDER: S-EPMC3884261 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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[1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-κ(2) P,P'](η(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-κC}ruthenium(II) hexa-fluorido-phosphate.

Zeng Ling-Zhen LZ Wu Yun-Ying YY Tian Guang-Xuan GX Li Zhen Z

Acta crystallographica. Section E, Structure reports online 20131019 Pt 11

In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the Ru(II) atom is coordinated by a cyclo-penta-dienyl ring in an η(5)-mode, one C atom from a 4,4'-diethynyl-1,1'-biphenyl ligand and two P atoms from a chelating 1,1'-bis-(di-phenyl-phosphan-yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C-H⋯F hydrogen bonds link the complex cations and hexa-fluorido-phosphate anions into a three-dimensional supra-molecular structure. ...[more]

PMID: 24454037

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