Browse
Submit Data
Databases
API
Help

Dataset Information

26 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-?(2) P,P'](?(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-?C}ruthenium(II) hexa-fluorido-phosphate.

ABSTRACT: In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the Ru(II) atom is coordinated by a cyclo-penta-dienyl ring in an ?(5)-mode, one C atom from a 4,4'-diethynyl-1,1'-biphenyl ligand and two P atoms from a chelating 1,1'-bis-(di-phenyl-phosphan-yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C-H?F hydrogen bonds link the complex cations and hexa-fluorido-phosphate anions into a three-dimensional supra-molecular structure.

SUBMITTER: Zeng LZ

PROVIDER: S-EPMC3884261 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-κ(2) P,P'](η(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-κC}ruthenium(II) hexa-fluorido-phosphate.

Zeng Ling-Zhen LZ Wu Yun-Ying YY Tian Guang-Xuan GX Li Zhen Z

Acta crystallographica. Section E, Structure reports online 20131019 Pt 11

In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the Ru(II) atom is coordinated by a cyclo-penta-dienyl ring in an η(5)-mode, one C atom from a 4,4'-diethynyl-1,1'-biphenyl ligand and two P atoms from a chelating 1,1'-bis-(di-phenyl-phosphan-yl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C-H⋯F hydrogen bonds link the complex cations and hexa-fluorido-phosphate anions into a three-dimensional supra-molecular structure. ...[more]

PMID: 24454037

Similar Datasets

[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-?P,P']chlorido(?-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.

Project description:In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo-penta-dienyl ring, a Cl atom and two P atoms of the chelating 1,1'-bis-(dicyclo-hexyl-phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (-) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898?(7):0.102?(7). The components are linked by C-H?F and C-H?Cl hydrogen bonds.

| S-EPMC2979948 | biostudies-literature

(?-Cyclo-penta-dien-yl)(?-mesitylamine)ruthenium(II) hexa-fluorido-phosphate.

Project description:The title compound, [Ru(?(5)-C(5)H(5)){?(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107?(3)?Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005?Å. N-H?F hydrogen-bonding interactions help to consolidate the crystal packing.

| S-EPMC2969571 | biostudies-literature

(η-Penta-methyl-cyclo-penta-dien-yl)(η-toluene)-ruthenium(II) hexa-fluorido-phosphate.

Project description:In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclo-penta-dienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C-H⋯F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies.

| S-EPMC2983397 | biostudies-literature

[1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.

Project description:In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1'-bis-(diphenyl-phosphan-yl)cobaltocenium ligand and a triphenyl-phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa-hedral geometry. In the cobaltocenium unit, the two cyclo-penta-dienyl rings are almost parallel, making a dihedral angle of 1.2?(3)°. The F atoms of the hexa-fluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849?(11):0.151?(11). Intra-molecular C-H?Cl hydrogen bonds occur in the complex cation. The complex cations, hexa-fluoridophosphate anions and dichloro-methane solvent mol-ecules are linked by inter-molecular C-H?F hydrogen bonds.

| S-EPMC3238603 | biostudies-literature

1,1'-Bis(diisobutyl-phosphino)cobalto-cenium hexa-fluorido-phosphate.

Project description:In the title compound, [Co(C(13)H(22)P)(2)]PF(6), the Co(III) atom is sandwiched between two (diisobutyl-phosphino)cyclo-penta-dienenyl ligands. The two diisobutyl-phophine units are trans to each other with respect to the Co(III) metal center. The PF(6) (-) anion links the cobaltocenium cations via weak C-H?F hydrogen bonds into a chain running along the b axis. The chains are further linked by C-H?F hydrogen bonds, forming a layer extending parallel to the (10) plane.

| S-EPMC2961756 | biostudies-literature

(η-Cyclo-penta-dien-yl)[η-diethyl eth-yl(phen-yl)malonate]iron(II) hexa-fluorido-phosphate.

Project description:At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (-) anion were found to be equally disordered over two sites.

| S-EPMC2959750 | biostudies-literature

[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-?(2)P,P'](?(5)-cyclo-penta-dien-yl)(dicyanamido-?N)ruthenium(II) dichloro-methane monosolvate.

Project description:The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1'-bis-(diphenyl-phosphan-yl)ferrocene] with sodium dicyanamide in dichloro-methane. The Ru(II) atom is capped by an ?(5)-cyclo-penta-dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C-N-C angle of the N(CN)(2) ligand [120.8?(6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2?(9)°; Zhang et al. (2003 ?). Inorg. Chem.42, 633-640] due to steric hindrance between the two {Cp(PPh(3))(2)Ru} building blocks. Disorder was found in the dichloro-methane solvent mol-ecule, which was refined as disordered over two positions, with a site-occupancy ratio of 0.53:0.47?(2).

| S-EPMC3344313 | biostudies-other

Tri-μ-chlorido-bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III)] hexa-fluorido-phosphate from synchrotron radiation.

Project description:In the title complex salt, [{(η(5)-C5Me5)Rh}2(μ-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C5Me5)RhCl3 'piano-stool' units by bridging of the three choride ligand 'legs'. The crystal structure shows several close H⋯F contacts between the hexa-fluorido-phosphate counter-ions and the C5Me5 ligands.

| S-EPMC4029212 | biostudies-literature

Acetonitrile-dicarbon-yl(?-penta-methyl-cyclo-penta-dien-yl)iron(II) tetra-fluorido-borate.

Project description:In the structure of the title compound, [Fe{?(5)-C(5)(CH(3))(5)}(NCCH(3))(CO)(2)]BF(4), the arrangement of ligands around the Fe atom is in a pseudo-octa-hedral three-legged piano-stool fashion in which the penta-methyl-cyclo-penta-dienyl (Cp*) ligand occupies three apical coordination sites, while the two carbonyl and one acetonitrile ligands form the basal axes of the coordination. The Fe-N bond length is 1.924?(3)?Å and the Fe-Cp* centroid distance is 1.722?Å.

| S-EPMC3151746 | biostudies-literature

(?-Benzophenone)(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate.

Project description:The structure of the title compound, [Ru(C(10)H(15))(C(13)H(10)O)](C(24)H(20)B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetra-phenyl-borate anions (Cp* = penta-methyl-cyclo-penta-dien-yl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42?(1) and 1.38?(1)?Å for the C-C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5?(1)°.

| S-EPMC2971317 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data