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Bis(2,2'-bipyridyl-?N,N')(carbonato-?O,O')cobalt(III) bromide trihydrate.

ABSTRACT: The title complex, [Co(CO(3))(C(10)H(8)N(2))(2)]Br·3H(2)O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2'-bipy)(2)CO(3)](+) cation (2,2'-bipy is 2,2'-bipyrid-yl), bromide ion and water mol-ecules are linked together via O-H?Br and O-H?O hydrogen bonds, generating a one-dimensional chain.

SUBMITTER: Ma PT

PROVIDER: S-EPMC2914907 | biostudies-other | 2007

REPOSITORIES: biostudies-other

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Bis(2,2'-bipyridyl-κN,N')(carbonato-κO,O')cobalt(III) bromide trihydrate.

Ma Peng-Tao PT Wang Yu-Xia YX Zhang Guo-Qian GQ Li Ming-Xue MX

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The title complex, [Co(CO(3))(C(10)H(8)N(2))(2)]Br·3H(2)O, is isostructural with the chloride analogue. The six-coordinated octahedral [Co(2,2'-bipy)(2)CO(3)](+) cation (2,2'-bipy is 2,2'-bipyrid-yl), bromide ion and water mol-ecules are linked together via O-H⋯Br and O-H⋯O hydrogen bonds, generating a one-dimensional chain. ...[more]

PMID: 21200495

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