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Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-?N,P}palladium(II) dichloro-methane hemi-solvate.

ABSTRACT: There are two independent Pd(II) complex mol-ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol-ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene ligand and two chloride anions.

SUBMITTER: Liu H

PROVIDER: S-EPMC2967851 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}palladium(II) dichloro-methane hemi-solvate.

Liu Huanyu H Shen Dongsheng D

Acta crystallographica. Section E, Structure reports online 20081203 Pt 1

There are two independent Pd(II) complex mol-ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol-ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene ligand and two chloride anions. ...[more]

PMID: 21581545

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