Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[trimethyl-tin(IV)]-?-2,5-difluoro-benzoato-?O:O'].

ABSTRACT: In the title polymeric coordination compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the carboxyl-ate O atoms in the axial positions and the equatorial positions occupied by the methyl groups. The two Sn-O bond lengths are 2.225?(5) and 2.410?(6)?Å.

SUBMITTER: Wen L

PROVIDER: S-EPMC2967876 | biostudies-other | 2008 Dec

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

catena-Poly[[trimethyl-tin(IV)]-μ-2,5-difluoro-benzoato-κO:O'].

Wen Liyuan L Yin Handong H Li Wenkuan W Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the carboxyl-ate O atoms in the axial positions and the equatorial positions occupied by the methyl groups. The two Sn-O bond lengths are 2.225 (5) and 2.410 (6) Å. ...[more]

PMID: 21581502

Similar Datasets

catena-Poly[[trimethyl-tin(IV)]-?-3,5-difluoro-benzoato-?O:O'].

Project description:In the title compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the central Sn atom is coordinated by two O atoms from the anion and three methyl C atoms in a polymeric fashion owing to the presence of bidentate bridging carboxyl-ate ligands. The five-coordinate Sn atom exists in a distorted trigonal-bipyramidal geometry with the mol-ecules connected by weak C-H?F inter-moleclar inter-actions, forming supra-molecular chains parallel to [010].

| S-EPMC3212122 | biostudies-literature

catena-Poly[[aqua-trimethyl-tin(IV)]-{[trimethyl-tin(IV)]-?(3)-thio-phene-2,5-dicarboxyl-ato}].

Project description:In the title compound, [Sn(2)(CH(3))(6)(C(6)H(2)O(4)S)(H(2)O)](n), each of the two crystallographically independent Sn atoms exhibits a distorted trigonal-bipyramidal coordination geometry formed by two O and three C atoms. The coordinated water mol-ecule plays an important role in crystal packing consolidation via O-H?O hydrogen bonding.

| S-EPMC2968262 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2,4,6-trichloro-benzoato].

Project description:In the title compound, [Sn(CH(3))(3)(C(7)H(2)Cl(3)O(2))](n), the tin(IV) atom exhibits a slightly distorted trigonal-bipyramidal geometry with two O atoms of symmetry-related carboxyl-ate groups in the axial positions and three methyl groups in the equatorial positions. In the crystal structure, the metal atoms are linked by carboxyl-ate bridges into polymeric chains extending along the b axis.

| S-EPMC2967877 | biostudies-other

catena-Poly[[trimethyl-tin(IV)]-μ-quinaldato].

Project description:The title compound, [Sn(CH(3))(3)(C(10)H(6)NO(2))](n), forms an extended one-dimensional chain structure. There are two independent Sn(IV) ions, both of which are in slightly distorted trigonal-bipyramidal coordination environments with two symmetry-related O atoms in the axial sites. In each case, the Sn(IV) ion and one of the three equatorial C atoms lie on a crystallographic twofold axis.

| S-EPMC2914916 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-phenyl-butano-ato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(10)H(11)O(2))](n), the Sn atom has a distorted trigonal-bipyramidal coordination geometry, with two O atoms of two symmetry-related carboxyl-ate ligands in axial positions and three methyl groups in equatorial positions. In the crystal structure, carboxyl-ate bridges link the metal atoms, forming zigzag chains parallel to the b axis.

| S-EPMC3011523 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-(2-chloro-phenyl)-acetato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(8)H(6)ClO(2))](n), the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl-ate O atoms of the 2-chloro-phenyl-acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chloro-phenyl-acetato ligand, forming a chain structure.

| S-EPMC2970316 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

| S-EPMC3051585 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-(1,1'-binaphthyl-2,2'-diyl phospho-nato)].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(20)H(12)O(4)P)](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the phosphate O atoms of the 1,1'-binaphthyl-2,2'-diyl phospho-nate ligands in axial positions and equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 1,1'-binaphthyl-2,2'-diyl phospho-nate ligand, forming a one-dimensional chain structure parallel to the b axis.

| S-EPMC2980144 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-cyclo-hex-3-ene-1-carboxyl-ato].

Project description:The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H?O hydrogen bond.

| S-EPMC2980015 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-(3-thien-yl)acetato].

Project description:The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799?(9)/0.201?(9) and 0.618?(7)/0.382?(7), respectively.

| S-EPMC2967881 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data