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Poly[bis-(1-carbamoylguanidinium) [tri-?-chlorido-dichloridobismuthate(III)]].


ABSTRACT: The structure of the title organic-inorganic hybrid compound, {(C(2)H(7)N(4)O)(2)[BiCl(5)]}(n), consists of corrugated chains parallel to [100] of corner-joined [BiCl(6)] octa-hedra, separated by layers of organic 1-carbamoylguanidinum cations. The crystal cohesion is achieved by N-H?O and N-H?Cl hydrogen bonds, which link the organic and inorganic parts of the structure.

SUBMITTER: Ferjani H 

PROVIDER: S-EPMC3344350 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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Poly[bis-(1-carbamoylguanidinium) [tri-μ-chlorido-dichloridobismuthate(III)]].

Ferjani Hel H   Boughzala Habib H   Driss Ahmed A  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5


The structure of the title organic-inorganic hybrid compound, {(C(2)H(7)N(4)O)(2)[BiCl(5)]}(n), consists of corrugated chains parallel to [100] of corner-joined [BiCl(6)] octa-hedra, separated by layers of organic 1-carbamoylguanidinum cations. The crystal cohesion is achieved by N-H⋯O and N-H⋯Cl hydrogen bonds, which link the organic and inorganic parts of the structure. ...[more]

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