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Dichlorido[2-diphenyl-phosphanyl-N-(pyridin-3-ylmeth-yl)benzyl-idenamine-κP,N]platinum(II).

ABSTRACT: The title compound, [PtCl(2)(C(25)H(21)N(2)P)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the metal is coordinated to the imino N and phosphane P atoms of the ligand and to two chloride ions. The Pt(II) atom is in a distorted square-planar environment and is bound to the ligand via the P and amine N atoms in a cis fashion, with the chlorine atoms located at the two remaining sites.

SUBMITTER: Chiririwa H

PROVIDER: S-EPMC3246929 | biostudies-literature |

REPOSITORIES: biostudies-literature

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[N-Benzyl-N-(diphenyl-phosphanylmeth-yl)pyridin-2-amine]-chloridomethyl-platinum(II).

Project description:In the mononuclear title complex, [Pt(CH(3))Cl(C(25)H(23)N(2)P)], the N-benzyl-N-(diphenyl-phosphanylmeth-yl)pyridin-2-amine functions as a bidentate ligand with the pyridyl N atom and the phosphine P atom chelating the Pt(II) ion, forming a six-membered metallocycle. The Pt(II) atom adopts a square-planar coordination geometry with one methyl group and one chloride ligand bonding to the metal center in a cis relationship. C-H?? and C-H?Cl inter-actions help to consolidate the packing.

| S-EPMC3050312 | biostudies-other

(SP-4-2)-Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]benzyl-amine-κP,N}(meth-yl)palladium(II).

Project description:In the title Pd(II) complex, [Pd(CH(3))Cl(C(26)H(22)NP)], the Pd(II) atom is coordinated in a slightly distorted square-planar geometry by the imino N and phosphane P atoms of the ligand, by one chloride ion and by a methyl ligand. The methyl group is trans to the N atom of the ligand.

| S-EPMC3246930 | biostudies-literature

[(1R*,2S*)-N-Benzyl-2-phenyl-1-(pyridin-2-yl)-N-(pyridin-2-ylmeth-yl)ethane-1,2-diamine]-dichloridozinc(II).

Project description:In the mononuclear zinc title complex, [ZnCl(2)(C(26)H(26)N(4))], the Zn(II) ion is surrounded by three N atoms from a (1R*,2S*)-N(1)-benzyl-2-phenyl-1-(pyridin-2-yl)-N(2)-(pyridin-2-ylmeth-yl)ethane-1,2-diamine (BPPPEN) ligand and two terminal chloride ligands, resulting in a highly distorted environment around the metal atom. The calculated τ parameter of 0.42 indicates that the coordination geometry is approximately square-pyramidal. Hydrogen bonds involving centrosymmetric N-H⋯Cl inter-actions form dimeric structures. The mol-ecules are stacked along the a and b axes.

| S-EPMC3052059 | biostudies-literature

Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline-κP,N}platinum(II).

Project description:The title compound, [PtCl(2)(C(31)H(32)NP)], is a Pt(II) complex with an NPCl(2) coordination sphere in which the Pt(II) atom is coordinated to the imino N and phosphane P atoms of the ligand and to two cis Cl ions, giving a slightly distorted square-planar geometry. The P-Pt-N angle is 89.80 (5)° and the corresponding angle between the Cl ions is 87.92 (2)°.

| S-EPMC3246928 | biostudies-literature

[N,N-Bis(diphenyl-phosphan-yl)benzyl-amine-κP,P']dichloridonickel(II) dichloro-methane monosolvate.

Project description:In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis-(diphenyl-phosphan-yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crystal, the components are linked by C-H⋯Cl inter-actions.

| S-EPMC3246988 | biostudies-literature

N-Diphenyl-phosphanyl-N-{[diphen-yl(2-pyridyl-imino)-?-phosphan-yl]meth-yl}pyridin-2-amine.

Project description:In the title compound, C(35)H(30)N(4)P(2), the diphenyl-phosphanyl and diphen-yl(2-pyridyl-imino)-?(5)-phosphanyl groups are attached to the central methyl C atom with a P-C-N angle of 114.09?(16)°. The mol-ecules stack along the b axis and inter-connect through C-H(pyrid-yl)?N(pyrid-yl) inter-actions, forming an infinite chain structure. The parallel chains are further inter-connected via C-H(benzene)?N(amino) and C-H(benzene)?? inter-actions, forming a three-dimensional framework.

| S-EPMC3201310 | biostudies-literature

Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-?N,P}platinum(II) dichloro-methane hemisolvate.

Project description:In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.

| S-EPMC2968145 | biostudies-literature

Crystal structure of (E)-(benzyl-idene)(pyridin-2-ylmeth-yl)amine.

Project description:In the title mol-ecule, C13H12N2, all non-H atoms, except for those of the pyridine ring, are essentially coplanar, with an r.m.s. deviation of 0.025?Å. The mean plane of these atoms forms a dihedral angle of 80.98?(4)° with the pyridine ring. In the crystal, weak C-H?? inter-actions link the mol-ecules, forming a three-dimensional network.

| S-EPMC4719968 | biostudies-literature

Chlorido(chloro-diphenyl-phosphine-κP)(diphenyl-piperidinophosphine-κP)(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II).

Project description:The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chloro-diphenyl-phosphine ligand formed from the diphenyl-piperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P-Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru-P bond lengths of 2.2598 (5) Å for the chloro-phosphine and 2.3303 (5) Å for the amino-phosphine.

| S-EPMC2977503 | biostudies-literature

Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-?P,N}platinum(II) dichloro-methane hemisolvate.

Project description:The crystal structure of the title compound, [PtCl(2)(C(25)H(22)NPS)]·0.5CH(2)Cl(2), was determined to establish the coordination properties of the (phosphan-yl)benzyl-idene-methanamine ligand to platinum. In the unit cell two mol-ecules of cis-[PtCl(2)(C(25)H(22)NPS)] are accompanied by a dichloro-methane solvent mol-ecule. The square-planar Pt(2+) coordination sphere is slightly distorted with the bidentate ligand coordinated via the P and the amine N atoms, and the Cl atoms located cis at the two remaining coordination sites. Parts of the thiophene ring and the solvate molecule were modeled as disordered with occupancy ratios of 0.55?(2):0.45?(2) and 0.302?(10):0.198?(10), respectively. Weak C-H?Cl inter-actions stabilize the crystal packing.

| S-EPMC3274858 | biostudies-other

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