Unknown

Dataset Information

0

Cis-Dichloridobis(ethyl methyl sulfide-?S)oxidovanadium(IV).

ABSTRACT: The mononuclear title complex, [VCl2O(C3H8S)2], features a V(IV)=O double bond [1.5845?(15)?Å] in an overall trigonal-bipyramidal coordination environment defined by two Cl(-) and the S atoms of two (CH3CH2)(CH3)S ligands. In the crystal, pairs of mol-ecules form centrosymmetric dimers via C-H?O hydrogen bonds between the methyl C-H group and the oxidovanadium O atom of a neighbouring mol-ecule.

SUBMITTER: Matsuura M 

PROVIDER: S-EPMC3629486 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

cis-Dichloridobis(ethyl methyl sulfide-κS)oxidovanadium(IV).

Matsuura Masatoshi M   Fujihara Takashi T   Nagasawa Akira A  

Acta crystallographica. Section E, Structure reports online 20130316 Pt 4

The mononuclear title complex, [VCl2O(C3H8S)2], features a V(IV)=O double bond [1.5845 (15) Å] in an overall trigonal-bipyramidal coordination environment defined by two Cl(-) and the S atoms of two (CH3CH2)(CH3)S ligands. In the crystal, pairs of mol-ecules form centrosymmetric dimers via C-H⋯O hydrogen bonds between the methyl C-H group and the oxidovanadium O atom of a neighbouring mol-ecule. ...[more]

Similar Datasets

Unknown Dichloridobis(2-methyl-quinolin-8-olato-?N,O)tin(IV).
| S-EPMC2969261 | biostudies-literature
Unknown cis-Dichloridobis[tris-(2-methyl-phen-oxy)phosphane-?P]palladium(II).
| S-EPMC3297231 | biostudies-literature
Unknown Dichloridobis(di-tert-butyl-methyl-phosphine oxide-?O)diphenyl-tin(IV).
| S-EPMC2961504 | biostudies-literature
Unknown Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-?N,N')tin(IV).
| S-EPMC2983632 | biostudies-literature
Unknown cis-Chloridobis(4,4'-dimethyl-2,2'-bipyridine-?(2)N,N')oxidovanadium(IV) chloride ethanol monosolvate monohydrate.
| S-EPMC3470179 | biostudies-literature
Unknown cis-Dichloridobis{[4-(dimethyl-amino)-phen-yl]diphenyl-phosphane-?P}platinum(II) ethyl acetate monosolvate.
| S-EPMC3201384 | biostudies-literature
Unknown Di-?-chlorido-bis-[diacetonitrile-chlorido-oxidovanadium(IV)].
| S-EPMC3201240 | biostudies-literature
Unknown A monoclinic polymorph of di-μ-oxido-bis-({2-[2-(methyl-amino)ethyl-imino-methyl]phenolato-κN,N',O}oxidovanadium(V)).
| S-EPMC2959960 | biostudies-literature
Unknown cis-Dichloridobis(triisopropoxy-phosphine)-platinum(II).
| S-EPMC2971432 | biostudies-literature
Unknown Crystal structure of {2,2'-[ethyl-enebis(nitrilo-methanylyl-idene)]diphenolato-?(4) O,N,N',O'}oxidovanadium(IV) methanol monosolvate.
| S-EPMC4257326 | biostudies-literature