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Bis-(chloro-acetato-?O)bis(trimethyl-silylmethyl)tin(IV).


ABSTRACT: In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(4)H(11)Si)(2)], the Sn(IV) ion is coordinated in a distorted tetra-hedral environment formed by two O atoms from two monodenate chloro-acetato ligands and two C atoms from two trimethyl silyl ligands. Two further weak intra-molecular Sn?O contacts [2.744?(2) and 2.655?(2)?Å] are formed by the chloro-acetato ligands.

SUBMITTER: Ding RF 

PROVIDER: S-EPMC3200893 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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Bis-(chloro-acetato-κO)bis(trimethyl-silylmethyl)tin(IV).

Ding Rui-Fang RF   Wang Qi-Bao QB  

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9


In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(4)H(11)Si)(2)], the Sn(IV) ion is coordinated in a distorted tetra-hedral environment formed by two O atoms from two monodenate chloro-acetato ligands and two C atoms from two trimethyl silyl ligands. Two further weak intra-molecular Sn⋯O contacts [2.744 (2) and 2.655 (2) Å] are formed by the chloro-acetato ligands. ...[more]

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