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[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

ABSTRACT: In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09?(5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au?O = 2.959?(4)?Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971876 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au⋯O = 2.959 (4) Å]. ...[more]

PMID: 21578659

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